NIST Atomic Spectra Database - Addition of the Monograph 8 Data

Report on changes made to ASD and Monograph 8

A. E. Kramida, August 7, 2003

Introduction

In order to merge energy levels and lines lists from the two databases, some changes had to be made in both databases. These changes are divided into the following categories:

- Energy level changes

o Configuration naming changes

o Term label changes

o Energy value changes

o J-value changes

o Percentage composition changes

- Line changes

o Line identification changes

o Wavelength changes

o Transition probability changes

o Observed intensity changes

o Lines deleted

o Lines added

These changes will be described separately for Monograph 8 and ASD, although they are closely related, since the purpose of the changes was to establish a correspondence between the data that already existed in ASD and the new data in Monograph 8.

1. Changes made to Monograph 8 data.

1.1. Energy level changes in Monograph 8

1.1.1. Configuration naming changes in Monograph 8

Initially, Monograph 8 contained 8658 distinct energy level definitions appearing in the upper and lower level descriptions. The final mono8_levels table contains only 8543 energy levels. Some of the levels were defined several times in Monograph 8 with some slight differences, e.g. energy of the ground state one time given as ‘0.0’ and another time as just ‘0’, or one time a complete shell (1s², 2s², 2p⁶, etc.) included in the configuration name, and another time this shell not included. The second category was the most numerous. Since ASD had a similar problem of duplicate levels and inconsistent configuration naming, we had to apply a general approach of consistent configuration naming along isoelectronic sequences, using ASD as a main supply for the various naming cases. As a result, configuration name was changed for about 2000 levels in Monograph 8. The approach was approximately as follows:

- We selected all distinct configuration names in every isoelectronic sequence used in ASD and exist in ASD for these lines.

- Along each isoelectronic sequence, we checked if there are any cases where the previous complete shell was included in the configuration name. For example, for the Li I isoelectronic sequence, some spectra contained 1s² shell in the configuration name, and some did not. Also, some spectra had a ¹S parent term included for this shell, and some did not have it. The actions in this case were as follows:

o Include 1s² in all configuration names like nl;

o Delete the (¹S) parent term from configurations defined similar to 1s²(¹S)4s.

Aside from the completed shells removal, the configuration label was changed for several levels either because of an error in the designation or based on the percentage composition analysis. These cases are described in the following section, “Term label changes”, because they usually involved a change in the term designation, too.

1.1.2. Term label changes in Monograph 8

The term labels were changed for 227 levels in Monograph 8.

In 137 cases, the term label was given in Jl coupling without the leading superscript ‘2’ (e.g. [15/2]*), and we added the leading ‘2’. Such changes were made in the Mo VII, Ti III, and V IV spectra. A detailed list is not given here because this change is pretty obvious.

The remaining 90 cases are listed below. Most of them result from an effort to bring the term naming convention to the one discussed between the group members, namely, that the term labels must be consistent within every configuration, and every level must have a unique label within a configuration. The corresponding percentages from the merged (ASD + Monograph8) database are given to provide a hint why the term label was changed.

The Fe VIII 3p⁵3d(¹F^o) 4s ²F^o_5/2 (884331) and 3p⁵3d(¹D^o)4s ²D^o_5/2 (879021) level designations are switched compared to their definitions in Monograph 8 that were cited from the paper of Ramonas and Ryabtsev, Opt. Spektrosk. 48, pp.631-638 (1980). The new designations are taken from the current ASD database. The higher level, according to ASD, has 46% of (¹F^o)²F^o and 27% of (¹D^o)²D^o that could be the reason for naming it as (¹D^o)²D^o in the original paper. However, the lower level, according to ASD, has 46% of (¹D^o)²D^o and 25% of (³D^o)²D^o which makes it doubtful why Ramonas and Ryabtsev assigned it a (¹F^o)²F^o label. There is no explicit reference in ASD to the source of the given percentage compositions. However, the term splittings appear to be consistent with ASD term labels, so it was decided to retain the ASD term labels.

The Kr XVIII level at 15062000 cm^-1 was listed as (¹S₀, 3/2) (41%, the leading component) in the original paper of Burkhalter, Shiloh, Fisher, and Cowan, J.Appl.Phys., 50(7), 4532 (1979). In ASD, it was labeled as (³P₂, 3/2) without a percentage value. Two independent Cowan calculations of this spectrum produced percentage compositions and energy splittings that basically agreed with the original paper of Burkhalter et al., except for the fact that the leading component of this term is 36% of (³P₀, 3/2) instead of (¹S₀, 3/2), but the latter character has the second largest contribution (34%) in this eigenstate. Thus, this level was labeled as 2s²2p⁴(³P₀)3d (0,3/2), J = 3/2, and assigned the percentages resulting from the calculations. We could not assign to this level the label used by Burkhalter et al. (and thus given in Monograph 8) because ASD already has a level at 15953000 cm-1 having this label with the same J value. This level agrees with both Cowan calculations.

The Mo IX level with J=1 at 447509 cm^-1 was labeled 4s²4p³(⁴S^o)4d ³D^o in Monograph 8, but it was designated as 4s²4p³4d ³D^o (40%) in ASD, with the second component of 4s²4p³(⁴S^o)4d ³D^o (31%). The parent term of the leading component was not given in ASD. We performed Cowan calculations of this spectrum, having included 19 configurations of odd parity. The configurations set was 4s4p⁵, 4s²4p³ns and nd (n = 4,5,6,7), 4p⁵ns and nd (n = 4,5,6,7), 4s²4p4d³, 4s²4p4d³, 4s²4p4d²5s, 4s4p³4d5s, and 4s4p³4d². The 4s²4p³4d configuration was reproduced fairly well, and it was found that the parent term for the level with J = 1 at 447509 is ²P^o. We obtained the percentage of this term 36%, and there are 34% of (⁴S^o)³D on the second place. This agrees fairly well with the percentages listed in ASD, so the ASD percentages are retained, only replaced the configuration name with 4s²4p³(²P^o)4d both in ASD and Monograph 8.

For the Mo XVIII level at 210770 cm^-1, the multiplicity was not given in the term designation for the line at 71.461 A. The multiplicity ‘2’ was given for this level for the line at 71.196 A, and this term designation was accepted.

The Mo XXXIII level at 31400000 cm^-1 was listed as unresolved 2s²2p⁵7d ³D^o₁ and 2s²2p⁵6d ³P^o₁. The second term name was changed to ¹P^o, because the ³P^o term was not observed for any of the 2p⁵nd configurations along the series, except for the lowest 2p⁵3d configuration, while the ¹P^o terms were observed. The original paper of Burkhalter et al., Phys. Rev. 18, 718 (1978) gives all 2p⁵nd levels in jj notation, however all of them are given in ASD in LS coupling scheme. This particular level at 31400000 cm^-1 was given as ¹P^o₁ in ASD, and this classification was retained.

In a number of cases, the levels were given in Monograph 8 in a different notation than in ASD, and the notation was changed so that the resulting merged data have a consistent notation within each configuration. To do that, Cowan-code calculations were done in some cases.

In Ti XII, the level with J=7/2 of the 2p⁵3s3p configuration with unknown energy was given with LS term name 4D. All other levels of this configuration, present in ASD (but missing in Monograph 8), are given in jj notation, so we changed this level’s designation to 2p⁵(²P^o_3/2)3s3p(³P^o₂) (3/2,2), J = 7/2. For the same reason, the designation of the 2p⁵3s3d ⁴F^o J = 9/2 level was changed to 2p⁵(²P^o_3/2)3s3d(³D₃) (3/2,3)^o.

The Ni XIX 2p⁵3d levels with J = 1 were all given in Monograph 8 in LS coupling scheme, the same as in ASD. The rest 9 levels, all new compared to ASD, were all given in jj notation. In addition, the lowest J = 1 level was given twice, once in LS notation with the old ASD energy derived from a soft X-ray line at 12.812 Å, and the other time in jj notation with a new energy derived from a VUV line (2p⁵3p-2p⁵3d) observed in a beam-foil source. We performed Cowan’s calculations and replaced LS notation with jj. For the lowest J = 1 level, the old energy (7805200 cm^-1) was also replaced with the new one (7807700 cm^-1). Now the X-ray line mentioned above has Ritz wavelength 12.808 Å which is 0.004 Å off the observed wavelength.

In Fe XII, levels at 501800 (J = 3/2) and 513850 cm^-1 (J = 1/2) have mixed contributions of 3s3p⁴ ²P and 3s²3p²(¹D)3d ²P characters. In Monograph 8, they were given no term labels but numerical indexes like ‘(3)’. We assigned them unique term labels based on LS percentage compositions listed in ASD. The resulting energy levels data for these two configurations looks as shown in the table below. The affected levels are highlighted.

Fe XII levels for which term labels were changed compared to Monograph 8.

+---------+-------+-----------------+------+-----------------+-------+------+-----------------+-------+-------+

+---------+-------+-----------------+------+-----------------+-------+------+-----------------+-------+-------+

| 288307 | 1/2 | 3s.3p4 | 4P | | | 88 | 3s2.3p2.(3P).3d | 4P | 9 |

| 394120 | 1/2 | 3s.3p4 | 2S | | | 41 | 3s.3p4 | 2P | 27 |

| 513850 | 1/2 | 3s.3p4 | 2P | | 2P | 35 | 3s2.3p2.(1D).3d | 2P | 32 |

| 519770 | 1/2 | 3s2.3p2.(3P).3d | 4P | | | 80 | 3s.3p4 | 4P | 8 |

| 568940 | 1/2 | 3s2.3p2.(1D).3d | 2P | | | 58 | 3s2.3p2.(3P).3d | 2P | 24 |

| 579630 | 1/2 | 3s2.3p2.(1D).3d | 2S | | | 72 | 3s.3p4 | 2S | 14 |

+---------+-------+-----------------+------+-----------------+-------+------+-----------------+-------+-------+

| 284005 | 3/2 | 3s.3p4 | 4P | | | 89 | 3s2.3p2.(3P).3d | 4P | 9 |

| 340020 | 3/2 | 3s.3p4 | 2D | | | 78 | 3s2.3p2.(1D).3d | 2D | 16 |

| 389706 | 3/2 | 3s.3p4 | 2P | | | 48 | 3s2.3p2.(3P).3d | 2P | 44 |

| 501800 | 3/2 | 3s2.3p2.(1D).3d | 2P | 3s.3p4 | 2P | 41 | 3s2.3p2.(1D).3d | 2P | 26 |

| 516740 | 3/2 | 3s2.3p2.(3P).3d | 4P | | | 82 | 3s.3p4 | 4P | 8 |

| 526120 | 3/2 | 3s2.3p2.(1S).3d | 2D | | | 46 | 3s2.3p2.(3P).3d | 2D | 40 |

| 554030 | 3/2 | 3s2.3p2.(1D).3d | 2D | | | 78 | 3s.3p4 | 2D | 14 |

| 577740 | 3/2 | 3s2.3p2.(3P).3d | 2P | 3s2.3p2.(1D).3d | 2P | 61 | 3s2.3p2.(3P).3d | 2P | 26 |

| 605480 | 3/2 | 3s2.3p2.(3P).3d | 2D | | | 55 | 3s2.3p2.(1S).3d | 2D | 41 |

+---------+-------+-----------------+------+-----------------+-------+------+-----------------+-------+-------+

The 3d⁸4p configuration of Mo XVI has an intermediate coupling scheme. No pure coupling yields purity higher than 59% for this configuration (jj coupling is the best one). In LS coupling, purity is 54%, which is not much worse. Most of the levels of this configuration (23 out of 33) had LS term labels in Monograph 8, the same as in ASD. The rest 10 levels were labeled with successive numerical indexes because the leading terms had very low percentage. In order to find proper labels for these levels, we performed Cowan-code calculations of the odd configurations. As a result of the ab initio calculations with F, G, and CI Slater integrals scaled at 90% of their Hartree-Fock values, almost all term labels assigned in ASD were confirmed, and the parent terms were found unambiguously where they were missing in ASD. Only one level's percentage composition was in total disagreement with the ASD data. It was the J = 3/2, E = 2171850 cm^-1 level. For this level, the percentage composition in ASD was changed based on our calculations. To make sure that the calculated percentage composition is stable against small variations of parameters, we performed two ab initio calculations, one with scaling of F, G, and CI integrals at 90%, and another one with scaling at 85%. In addition, a parametric fitting starting with the 90%-scaled HF calculation was made. Here are the results of these calculations for the level in question.

Percentage composition of the E= 2171850, J = 3/2 level of Mo XVI (configuration 3d⁸4p).

----------------------------------------------------------------------------------

(3P)2P* (3P)4D* (3F)2D* (1D)2D*

----------------------------------------------------------------------------------

After fit (90% scaling) 27% 22 17 11

Before fit (90% scaling) 28% 23 14 17

No fit (85% scaling) 30% 24 12 14

----------------------------------------------------------------------------------

Old ASD listing none none 15 11

----------------------------------------------------------------------------------

As readily seen from the above table, the percentages of the two leading components are fairly stable to small variations in the parameters. The following odd configurations were included in the Cowan calculations: 3s²3p⁶3d⁸4p, 3s²3p⁶3d⁸4f, 3s²3p⁵3d¹⁰, 3s²3p⁵3d⁹4s, 3s²3p⁵3d⁹4d, 3s3p⁶3d⁹4p, 3s3p⁶3d⁹4f, 3p⁶3d¹⁰4p, 3p⁶3d¹⁰4f. All other leading percentages listed in the old ASD were reproduced fairly well (but not always the second percentages, though).

Note that the best description of this configuration is in jj coupling (purity 59%). In LS coupling, purity is 54%. Despite this highly mixed coupling, the levels are very well described by their energy order in each J group. There were no variations in the level ordering by energy in various calculations. Thus, it might be reasonable to discard all LS labels for this configuration, and label all levels with successive numerical indexes. However, since the majority of the levels already had more or less proper LS term labels, it was decided to assign LS labels to all of them. The table below presents the results.

LS term labels and percentage composition of the 3d⁸4p configuration of Mo XVI. The column 'old_label' has the term label that was assigned to the level in ASD ver. 2.1 and 2.0.

+---------+-------+---------+-------+---------+-------+-----------+-----------+

+---------+-------+---------+-------+---------+-------+-----------+-----------+

| 2174130 | 1/2 | (3P)4D* | 50 | (3F)4D* | 26 | (3P)4D* | (3P)4D* |

| 2207180 | 1/2 | (3P)2S* | 61 | (3P)2P* | 19 | (3P)2S* | (3P)2S* |

| 2222200 | 1/2 | (1D)2P* | 32 | (3P)2P* | 31 | (1D)2P* | (1D)2P* |

| 2273700 | 1/2 | (1S)2P* | 88 | (1D)2P* | 4 | (1S)2P* | (1S)2P* |

| 2115910 | 3/2 | (3F)4F* | 20 | (3F)4D* | 6 | (3F)4D* | ( ?)* |

| 2146260 | 3/2 | (3P)4P* | 33 | (3F)4F* | 19 | (3P)4P* | ( ?)* |

| 2164610 | 3/2 | (3F)4F* | 40 | (3F)2D* | 16 | (3F)4F* | (3F)4F* |

| 2171850 | 3/2 | (3P)2P* | 27 | (3P)4D* | 22 | (3P)4D* | ( ?)* |

| 2178520 | 3/2 | (3F)2D* | 36 | (1D)2D* | 21 | (3F)2D* | (3F)2D* |

| 2190130 | 3/2 | (1D)2P* | 38 | (3P)2P* | 17 | (1D)2P* | (1D)2P* |

| 2198620 | 3/2 | (3P)4F* | 37 | (1D)2D* | 17 | (3P)2P* | ( ?)* |

| 2207920 | 3/2 | (3P)2D* | 69 | (3P)4D* | 9 | (3P)2D* | (3P)2D* |

| 2308160 | 3/2 | (1S)2P* | 91 | (1D)2P* | 2 | (1S)2P* | (1S)2P* |

| 2110510 | 5/2 | (3F)4D* | 60 | (3F)4F* | 18 | (3F)4D* | (3F)4D* |

| 2115860 | 5/2 | (3F)4G* | 46 | (1D)2F* | 19 | (3F)4G* | (3F)4G* |

| 2134880 | 5/2 | (3F)2D* | 41 | (3F)4G* | 26 | (3F)2D* | (3F)2D* |

| 2147170 | 5/2 | (3F)2D* | 32 | (3P)4P* | 20 | (3P)4P* | ( ?)* |

| 2151550 | 5/2 | (3F)4F* | 33 | (3F)2F* | 16 | (3F)4F* | ( ?)* |

| 2160220 | 5/2 | (3F)2F* | 36 | (1D)2F* | 15 | (3F)2F* | (3F)2F* |

| 2167740 | 5/2 | (3P)4P* | 28 | (1D)2F* | 22 | (1D)2F* | ( ?)* |

| 2179240 | 5/2 | (3F)2F* | 26 | (3P)2D* | 24 | (3P)2D* | ( ?)* |

| 2195590 | 5/2 | (1G)2F* | 30 | (1D)2D* | 24 | (1D)2D* | ( ?)* |

| 2203810 | 5/2 | (3P)4D* | 40 | (3P)2D* | 36 | (3P)4D* | (3P)4D* |

| 2212460 | 5/2 | (1G)2F* | 43 | (1D)2D* | 16 | (1G)2F* | (1G)2F* |

| 2085110 | 7/2 | (3F)4D* | 69 | (3F)4F* | 16 | (3F)4D* | (3F)4D* |

| 2114080 | 7/2 | (3F)4G* | 65 | (3F)2G* | 15 | (3F)4G* | (3F)4G* |

| 2134060 | 7/2 | (3F)2F* | 59 | (3F)4F* | 15 | (3F)2F* | (3F)2F* |

| 2156190 | 7/2 | (3F)4F* | 53 | (3F)2F* | 22 | (3F)4F* | (3F)4F* |

| 2157400 | 7/2 | (1D)2F* | 37 | (3F)2G* | 36 | (3F)2G* | ( ?)* |

| 2172780 | 7/2 | (1G)2F* | 64 | (3F)2G* | 14 | (1G)2F* | (1G)2F* |

| 2182980 | 7/2 | (3P)4D* | 56 | (3F)2G* | 14 | (3P)4D* | (3P)4D* |

| 2209940 | 7/2 | (1D)2F* | 48 | (3P)4D* | 30 | (1D)2F* | (1D)2F* |

| 2222220 | 7/2 | (1G)2G* | 77 | (1G)2F* | 17 | (1G)2G* | (1G)2G* |

+---------+-------+---------+-------+---------+-------+-----------+-----------+

Similarly, the 3p⁵3d⁸ configuration of Mo XVIII is far from pure coupling. In Monograph 8, all terms of this configuration were designated with successive numerical indexes in the order of increasing energy in each J group, as they were in the original paper by Wyart et al, Phys. Scr. 28, 381 (1983). In ASD ver. 2.0 and 2.1, most of these levels have LS percentage composition, and some of them have LS term labels. Thus, out of total 29 known levels of this configuration, 15 had LS term labels, and 14 had none. To find unique LS term labels for each level of this configuration, parametric fitting with Cowan's codes was performed. The parameters obtained in the fitting are rather close to those published by Wyart et al. However, here more configurations were included than in Wyart et al publication. The present configuration set included 3s²3p⁵3d⁸, 3s²3p³3d¹⁰, 3s²3p⁶4p, 3s²3p⁵3d⁷4s, 3s²3p⁵3d⁷4d, 3s3p⁵3d⁹, 3s3p⁶3d⁷4p, 3s⁰3p⁵3d¹⁰, and 3s⁰3p⁶3d⁸4p configurations, while Wyart's set consisted of 3p⁵3d⁸ alone. Thus, it is expected that the present percentage compositions should be rather close to the true ones. The old ASD compositions agree with the present results and those obtained by reproducing Wyart's calculations only qualitatively and only for the most pure states that had LS term labels in ASD. To assign LS term labels to all levels, including those five that were missing in ASD, the percentage compositions in ASD had to be replaced with the results of my calculations. After that, the labels could be assigned fairly easily.

In the table below, the left half shows percentage compositions and LS term labels resulting from my fitting, and the right half shows the same things from ASD ver. 2.0 and 2.1, where available.

+---------+-------+------+---------+------+---------+---------+--------+---------+--------+---------+---------+

+---------+-------+------+---------+------+---------+---------+--------+---------+--------+---------+---------+

| 1643278 | 1/2 | 78 | (1S)2P* | 21 | (3P)2P* | (1S)2P* | NULL | NULL | NULL | NULL | NULL |

| 1336120 | 3/2 | 36 | (3P)4P* | 21 | (3F)4F* | (3P)4P* | 40 | (3P)4P* | 17 | (3P)4D* | (3P)4P* |

| 1372180 | 3/2 | 38 | (3F)4D* | 23 | (1D)2D* | (3F)4D* | NULL | NULL | NULL | NULL | NULL |

| 1388018 | 3/2 | 29 | (3P)4S* | 25 | (3P)4D* | (3P)4S* | NULL | NULL | NULL | NULL | NULL |

| 1553198 | 3/2 | 41 | (1D)2D* | 27 | (1D)2P* | (1D)2D* | NULL | NULL | NULL | NULL | NULL |

| 1597386 | 3/2 | 46 | (3F)2D* | 22 | (3P)2D* | (3F)2D* | NULL | NULL | NULL | NULL | NULL |

| 1646000 | 3/2 | 60 | (3P)2P* | 14 | (3P)2D* | (3P)2P* | 61 | (3P)2P* | 12 | (3P)2D* | (3P)2P* |

| 1307600 | 5/2 | 38 | (3P)4P* | 25 | (3P)4D* | (3P)4P* | 47 | (3P)4P* | 30 | (3P)4D* | (3P)4P* |

| 1322740 | 5/2 | 37 | (3F)4F* | 31 | (3P)4P* | (3F)4F* | 45 | (3F)4F* | 22 | (3P)4P* | (3F)4F* |

| 1377840 | 5/2 | 33 | (3P)4D* | 30 | (3F)4D* | (3P)4D* | 31 | (3P)4D* | 22 | (3F)4G* | * |

| 1383380 | 5/2 | 35 | (3F)4G* | 20 | (1D)2D* | (3F)4G* | 27 | (3F)4D* | 20 | (3F)2D* | * |

| 1479650 | 5/2 | 22 | (1D)2D* | 19 | (1G)2F* | (1D)2D* | 23 | (1G)2F* | 21 | (1D)2D* | * |

| 1559730 | 5/2 | 43 | (1D)2F* | 31 | (3F)2F* | (1D)2F* | 39 | (1D)2F* | 32 | (3F)2F* | (1D)2F* |

| 1615600 | 5/2 | 60 | (3P)2D* | 22 | (3F)2D* | (3P)2D* | 58 | (3P)2D* | 23 | (3F)2D* | (3P)2D* |

| 1280420 | 7/2 | 29 | (3F)4G* | 29 | (3F)4F* | (3F)4G* | 36 | (3P)4D* | 31 | (3F)4G* | * |

| 1306770 | 7/2 | 64 | (3P)4D* | 12 | (3F)4F* | (3P)4D* | 54 | (3P)4D* | 13 | (3F)4G* | (3P)4D* |

| 1320790 | 7/2 | 30 | (1G)2G* | 20 | (3F)4F* | (1G)2G* | 30 | (3F)4F* | 27 | (1G)2G* | * |

| 1362690 | 7/2 | 27 | (1G)2G* | 23 | (1D)2F* | (1D)2F* | 26 | (1G)2G* | 22 | (1D)2F* | * |

| 1406680 | 7/2 | 37 | (3F)4D* | 28 | (3F)4F* | (3F)4D* | 35 | (3F)4D* | 26 | (3F)4F* | * |

| 1492600 | 7/2 | 42 | (3F)2F* | 19 | (3F)4D* | (3F)2F* | 40 | (3F)2F* | 24 | (3F)4D* | * |

| 1517570 | 7/2 | 49 | (3F)2G* | 40 | (1G)2F* | (3F)2G* | 52 | (3F)2G* | 34 | (1G)2F* | (3F)2G* |

| 1610200 | 7/2 | 34 | (1G)2F* | 26 | (3F)2G* | (1G)2F* | 41 | (1G)2F* | 24 | (1G)2G* | (1G)2F* |

| 1242360 | 9/2 | 83 | (3F)4G* | 16 | (3F)4F* | (3F)4G* | 86 | (3F)4G* | 12 | (3F)4F* | (3F)4G* |

| 1284110 | 9/2 | 46 | (3F)4F* | 25 | (1G)2G* | (3F)4F* | 46 | (3F)4F* | 26 | (1G)2G* | (3F)4F* |

| 1354790 | 9/2 | 41 | (1G)2G* | 32 | (3F)4F* | (1G)2G* | 38 | (1G)2G* | 35 | (3F)4F* | * |

| 1494810 | 9/2 | 74 | (1G)2H* | 13 | (3F)2G* | (1G)2H* | 71 | (1G)2H* | 15 | (3F)2G* | (1G)2H* |

| 1574310 | 9/2 | 66 | (3F)2G* | 24 | (1G)2G* | (3F)2G* | 63 | (3F)2G* | 27 | (1G)2G* | (3F)2G* |

| 1198630 | 11/2 | 99 | (3F)4G* | NULL | | (3F)4G* | 99 | (3F)4G* | NULL | | (3F)4G* |

| 1355000 | 11/2 | 99 | (1G)2H* | NULL | | (1G)2H* | 99 | (1G)2H* | NULL | | (1G)2H* |

+---------+-------+------+---------+------+---------+---------+--------+---------+--------+---------+---------+

There were several cases when the LS term labels given to levels in Monograph 8 were interchanged based on the percentage compositions in ASD. In the cases when the label chosen in ASD was based on the leading percentage, and the label used in Monograph 8 corresponded to the second percentage, the switching of the term labels is well justified, and these cases are not discussed in detail below .

The following table lists all cases when the term designations were changed.
+-------+-------------------------------+------------+-------+----------+------------+------+------+-----------------------+------------+-------+

+-------+-------------------------------+------------+-------+----------+------------+------+------+-----------------------+------------+-------+

| Co 18 | 2s2.2p5.(2P*<1/2>).3s | (1/2,1/2)* | 1 | 6592400 | 1P* | | or | | (1/2,1/2)* | |

| Co 18 | 2s2.2p5.(2P*<1/2>).4s | (1/2,1/2)* | 1 | 8833000 | 1P* | | or | | (1/2,1/2)* | |

| Co 18 | 2s2.2p5.(2P*<3/2>).3s | (3/2,1/2)* | 1 | 6477900 | 3P* | | or | | (3/2,1/2)* | |

| Co 18 | 2s2.2p5.(2P*<3/2>).4s | (3/2,1/2)* | 1 | 8706000 | 3P* | | or | | (3/2,1/2)* | |

| Cr 15 | 2s2.2p5.(2P*<1/2>).5d | 2[3/2]* | 1 | 7215000 | 1P* | | or | | 2[3/2]* | |

| Cr 15 | 2s2.2p5.(2P*<1/2>).6d | 2[3/2]* | 1 | 7524000 | 1P* | | or | | 2[3/2]* | |

| Cr 15 | 2s2.2p5.(2P*<3/2>).5d | 2[3/2]* | 1 | 7148000 | 3D* | | or | | 2[3/2]* | |

| Cr 15 | 2s2.2p5.(2P*<3/2>).6d | 2[3/2]* | 1 | 7452000 | 3D* | | or | | 2[3/2]* | |

| Fe 8 | 3p5.3d.(1D*).4s | 2F* | 5/2 | 879021 | 2D* | 48 | | 3p5.3d.(3D*).4s | 2D* | 25 |

| Fe 8 | 3p5.3d.(1F*).4s | 2D* | 5/2 | 884331 | 2F* | 46 | | 3p5.3d.(1D*).4s | 2D* | 27 |

| Fe 11 | 3s2.3p3.(2D*).3d | (5)* | 1 | 526480 | 3S | 38 | | 3s2.3p3.(2D*).3d | 3P | 23 |

| Fe 11 | 3s2.3p3.(2D*).3d | 3S | 1 | 533450 | 1P | 28 | | 3s2.3p3.(2D*).3d | 3S | 5 3 |

| Fe 12 | 3s.3p4 | 2P | 1/2 | 394120 | 2S | 41 | | 3s.3p4 | 2P | 27 |

| Fe 12 | 3s.3p4 | (3) | 1/2 | 513850 | 2P | 35 | | 3s2.3p2.(1D).3d | 2P | 32 |

| Fe 12 | 3s2.3p2.(1D).3d | (3) | 3/2 | 501800 | 2P (3s.3p4)| 41 | | 3s2.3p2.(1D).3d | 2P | 26 |

| Fe 16 | 2p5.(2P*<3/2>).3s.3p.(3P*<2>) | 4D | 7/2 | | (3/2,2) | | or | 2p5.3s.(3P*).3p | 4D | |

| Fe 16 | 2p5.(2P*<3/2>).3s.3d.(3D*<3>) | 4F* | 9/2 | | (3/2,3) | | or | 2p5.3s.(3P*).3d | 4F* | |

| Fe 17 | 2s2.2p5.3d | 3F* | 2 | 6506700 | 1D* | 41 | | 2s2.2p5.3d | 3F* | 35 |

| Fe 17 | 2s2.2p5.3d | 1D* | 2 | 6594360 | 3F* | 64 | | 2s2.2p5.3d | 1D* | 27 |

| Fe 17 | 2s2.2p5.3d | 1F* | 3 | 6515350 | 3D* | 64 | | 2s2.2p5.3d | 1F* | 34 |

| Fe 17 | 2s2.2p5.3d | 3D* | 3 | 6605150 | 1F* | 37 | | 2s2.2p5.3d | 3F* | 33 |

| Fe 17 | 2s2.2p5.3p | 3D | 1 | 6143850 | 1P | 50 | | 2s2.2p5.3p | 3D | 26 |

| Fe 17 | 2s2.2p5.3p | 1P | 1 | 6219030 | 3D | 67 | | 2s2.2p5.3p | 1P | 31 |

| Fe 17 | 2s2.2p5.3p | 1D | 2 | 6158470 | 3P | 67 | | 2s2.2p5.3p | 1D | 33 |

| Fe 17 | 2s2.2p5.3p | 3P | 2 | 6248260 | 1D | 41 | | 2s2.2p5.3p | 1D | 39 |

| Fe 18 | 2s.2p5.(3P*).3p | (1) | 3/2 | 7464400 | 4D | 38 | | 2s.2p5.(3P*).3p | 2P | 29 |

| Fe 18 | 2s2.2p4.(3P).3d | (2) | 3/2 | 6919000 | 4D | 29 | | 2s2.2p4.(3P).3d | 2P | 19 |

| Fe 18 | 2s2.2p4.(3P).3d | (1) | 5/2 | 6880400 | 2F | 26 | | 2s2.2p4.(3P).3d | 4P | 23 |

| Fe 19 | 2s2.2p3.(2D*<5/2>).3d | 3D* | 3 | 7396000 | (5/2,5/2)* | 44 | or | 2s2.2p3.(2D*).3d | 3D* | 74 |

| Fe 19 | 2s2.2p3.(2D*<5/2>).3d | (5/2,5/2)* | 3 | 7449000 | (5/2,3/2)* | 37 | or | 2s2.2p3.(2D*).3d | 1F* | 59 |

| Fe 23 | 1s2.2p.3d | (5)* | 2 | 12480000 | 3D* | 29 | | 1s2.2p.3d | 3P* | 35 |

| Fe 23 | 1s2.2p.4d | (2)* | 2 | 12480000 | 3D* | 44 | | 1s2.2p.4d | 3D* | 35 |

| Kr 10 | 3p6.3d8.(1G).4p | 4D* | 7/2 | 1016191 | 2F* | 40 | | 3p6.3d8.(3P).4p | 4D* | 28 |

| Kr 10 | 3p6.3d8.(3P).4p | 2F* | 7/2 | 1007600 | 4D* | 50 | | 3p6.3d8.(1G).4p | 2F* | 43 |

| Kr 21 | 3s2.3p3.(2P*).3d | 1F* | 3 | 968350 | 3D* | 38 | | 3s2.3p3.(4S).3d | 3D* | 30 |

| Kr 21 | 3s2.3p3.(4S*).3d | 3D* | 2 | 1007100 | 1D* | 24 | | 3s2.3p3.(4S*).3d | 3D* | 21 |

| Kr 24 | 3s.3p2 | 2S | 1/2 | 657825 | 2P | 61 | | 3s.3p2 | 2S | 33 |

| Kr 24 | 3s.3p2 | 2P | 1/2 | 754727 | 2S | 60 | | 3s.3p2 | 2P | 38 |

| Kr 28 | 2s2.2p4.(3P<0>).3d | (1S0,3/2) | 3/2 | 15062000 | (0,3/2) | 36 | | 2s2.2p4.(1S<0>).3d | (0,3/2) | 34 |

| Mn 16 | 2s2.2p5.(2P*<1/2>).5d | 2[3/2]* | 1 | 8084000 | 1P* | | or | | 2[3/2]* | |

| Mn 16 | 2s2.2p5.(2P*<1/2>).6d | 2[3/2]* | 1 | 8439000 | 1P* | | or | | 2[3/2]* | |

| Mn 16 | 2s2.2p5.(2P*<3/2>).5d | 2[3/2]* | 1 | 7994000 | 3D* | | or | | 2[3/2]* | |

| Mn 16 | 2s2.2p5.(2P*<3/2>).6d | 2[3/2]* | 1 | 8354000 | 3D* | | or | | 2[3/2]* | |

| Mo 7 | 4s2.4p5.(2P*<1/2>).7s | (1/2,1/2)* | 1 | 839342 | 2[1/2]* | | | | (1/2,1/2)* | |

| Mo 7 | 4s2.4p5.(2P*<1/2>).8s | (1/2,1/2)* | 1 | 898093 | 2[1/2]* | | | | (1/2,1/2)* | |

| Mo 7 | 4s2.4p5.(2P*<3/2>).10s | (3/2,1/2)* | 1 | 934536 | 2[3/2]* | | | | (3/2,1/2)* | |

| Mo 7 | 4s2.4p5.(2P*<3/2>).7s | (3/2,1/2)* | 1 | 816413 | 2[3/2]* | | | | (3/2,1/2)* | |

| Mo 7 | 4s2.4p5.(2P*<3/2>).8s | (3/2,1/2)* | 1 | 874998 | 2[3/2]* | | | | (3/2,1/2)* | |

| Mo 7 | 4s2.4p5.(2P*<3/2>).9s | (3/2,1/2)* | 1 | 910830 | 2[3/2]* | | | | (3/2,1/2)* | |

| Mo 9 | 4s2.4p3.4d | 3D* | 1 | 447509 | (9)* | 40 | | 4s2.4p3.(4S*).4d | 3D* | 31 |

| Mo 13 | 3d10.4s.5p | (1/2,1/2)* | 1 | 1126684 | 3P* | | or | | (1/2,1/2)* | |

| Mo 13 | 3d10.4s.5p | (1/2,3/2)* | 1 | 1139342 | 1P* | | or | | (1/2,3/2)* | |

| Mo 16 | 3p6.3d8.(1D).4p | (3)* | 5/2 | 2167740 | 2F* | 28 | | 3p6.3d8.(1D).4p | 2F* | 22 |

| Mo 16 | 3p6.3d8.(1D).4p | (5)* | 5/2 | 2195590 | 2D* | 30 | | 3p6.3d8.(1D).4p | 2D* | 24 |

| Mo 16 | 3p6.3d8.(3F).4p | (1)* | 3/2 | 2115910 | 4D* | 20 | | 3p6.3d8.(3F).4p | 4D* | 6 |

| Mo 16 | 3p6.3d8.(3F).4p | (2)* | 5/2 | 2151550 | 4F* | 33 | | 3p6.3d8.(3F).4p | 2F* | 16 |

| Mo 16 | 3p6.3d8.(3F).4p | (1)* | 7/2 | 2157400 | 2G* | 37 | | 3p6.3d8.(3F).4p | 2G* | 36 |

| Mo 16 | 3p6.3d8.(3P).4p | (2)* | 3/2 | 2146260 | 4P* | 33 | | 3p6.3d8.(3F).4p | 4F* | 19 |

| Mo 16 | 3p6.3d8.(3P).4p | (3)* | 3/2 | 2171850 | 4D* | 27 | | 3p6.3d8.(3P).4p | 4D* | 22 |

| Mo 16 | 3p6.3d8.(3P).4p | (4)* | 3/2 | 2198620 | 2P* | 37 | | 3p6.3d8.(1D).4p | 2D* | 17 |

| Mo 16 | 3p6.3d8.(3P).4p | (1)* | 5/2 | 2147170 | 4P* | 32 | | 3p6.3d8.(3P).4p | 4P* | 20 |

| Mo 16 | 3p6.3d8.(3P).4p | (4)* | 5/2 | 2179240 | 2D* | 26 | | 3p6.3d8.(3P).4p | 2D* | 24 |

| Mo 18 | 3p5.3d8.(1D) | (9)* | 3/2 | 1553198 | 2D* | 41 | | 3p5.3d8.(1D) | 2P* | 27 |

| Mo 18 | 3p5.3d8.(1D) | (9)* | 5/2 | 1479650 | 2D* | 22 | | 3p5.3d8.(1G) | 2F* | 19 |

| Mo 18 | 3p5.3d8.(1D) | (10)* | 5/2 | 1559730 | 2F* | 43 | | 3p5.3d8.(3F) | 2F* | 31 |

| Mo 18 | 3p5.3d8.(1D) | (5)* | 7/2 | 1362690 | 2F* | 27 | | 3p5.3d8.(1D) | 2F* | 23 |

| Mo 18 | 3p5.3d8.(1G) | (4)* | 7/2 | 1320790 | 2G* | 30 | | 3p5.3d8.(3F) | 4F* | 20 |

| Mo 18 | 3p5.3d8.(1G) | (9)* | 7/2 | 1610200 | 2F* | 34 | | 3p5.3d8.(3F) | 2G* | 26 |

| Mo 18 | 3p5.3d8.(1G) | (3)* | 9/2 | 1354790 | 2G* | 41 | | 3p5.3d8.(3F) | 4F* | 32 |

| Mo 18 | 3p5.3d8.(1G) | (4)* | 9/2 | 1494810 | 2H* | 74 | | 3p5.3d8.(3F) | 2G* | 13 |

| Mo 18 | 3p5.3d8.(1S) | (7)* | 1/2 | 1643278 | 2P* | 78 | | 3p5.3d8.(3P) | 2P* | 21 |

| Mo 18 | 3p5.3d8.(3F) | (1)* | 11/2 | 1198630 | 4G* | 99 | | | | |

| Mo 18 | 3p5.3d8.(3F) | (4)* | 3/2 | 1372180 | 4D* | 38 | | 3p5.3d8.(1D) | 2D* | 23 |

| Mo 18 | 3p5.3d8.(3F) | (10)* | 3/2 | 1597386 | 2D* | 46 | | 3p5.3d8.(3P) | 2D* | 22 |

| Mo 18 | 3p5.3d8.(3F) | (4)* | 5/2 | 1322740 | 4F* | 37 | | 3p5.3d8.(3P) | 4P* | 31 |

| Mo 18 | 3p5.3d8.(3F) | (6)* | 5/2 | 1383380 | 4G* | 35 | | 3p5.3d8.(1D) | 2D* | 20 |

| Mo 18 | 3p5.3d8.(3F) | (2)* | 7/2 | 1280420 | 4G* | 29 | | 3p5.3d8.(3F) | 4F* | 29 |

| Mo 18 | 3p5.3d8.(3F) | (7)* | 7/2 | 1492600 | 2F* | 42 | | 3p5.3d8.(3F) | 4D* | 19 |

| Mo 18 | 3p5.3d8.(3F) | (8)* | 7/2 | 1517570 | 2G* | 49 | | 3p5.3d8.(1G) | 2F* | 40 |

| Mo 18 | 3p5.3d8.(3F) | (1)* | 9/2 | 1242360 | 4G* | 83 | | 3p5.3d8.(3F) | 4F* | 16 |

| Mo 18 | 3p5.3d8.(3F) | (2)* | 9/2 | 1284110 | 4F* | 46 | | 3p5.3d8.(1G) | 2G* | 25 |

| Mo 18 | 3p5.3d8.(3F) | (5)* | 9/2 | 1574310 | 2G* | 66 | | 3p5.3d8.(1G) | 2G* | 24 |

| Mo 18 | 3p5.3d8.(3P) | (3)* | 3/2 | 1336120 | 4P* | 36 | | 3p5.3d8.(3F) | 4F* | 21 |

| Mo 18 | 3p5.3d8.(3P) | (5)* | 3/2 | 1388018 | 4S* | 29 | | 3p5.3d8.(3P) | 4D* | 25 |

| Mo 18 | 3p5.3d8.(3P) | (3)* | 5/2 | 1307600 | 4P* | 38 | | 3p5.3d8.(3P) | 4D* | 25 |

| Mo 18 | 3p5.3d8.(3P) | (5)* | 5/2 | 1377840 | 4D* | 33 | | 3p5.3d8.(3F) | 4D* | 30 |

| Mo 18 | 3p5.3d8.(3P) | (11)* | 5/2 | 1615600 | 2D* | 60 | | 3p5.3d8.(3F) | 2D* | 22 |

| Mo 18 | 3p5.3d8.(3P) | (3)* | 7/2 | 1306770 | 4D* | 64 | | 3p5.3d8.(3F) | 4F* | 12 |

| Mo 18 | 3p6.3d7 | D1 | 5/2 | 210770 | 2D1 | 71 | | 3p6.3d7 | 2D2 | 24 |

| Mo 30 | 3s.3p2 | 2D | 3/2 | 1150820 | 2P | 45 | | 3s2.3d | 2D | 32 |

| Mo 30 | 3s2.3d | 2P | 3/2 | 1080540 | 2D | 56 | | 3s.3p2 | 2P | 43 |

| Mo 33 | 2s2.2p5.6d | 3P* | 1 | 31400000 | 1P* | | | | | |

| Ni 19 | 2s2.2p5.(2P*<3/2>).3d | 3P* | 1 | 7807700 | (3/2,3/2) | 77 | or | 2s2.2p5.3d | 3P* | 91 |

| Ni 19 | 2s2.2p5.(2P*<3/2>).3d | 3D* | 1 | 7901400 | (3/2,5/2) | 64 | or | 2s2.2p5.3d | 3D* | 67 |

| Ni 19 | 2s2.2p5.(2P*<1/2>).3d | 1P* | 1 | 8041800 | (1/2,3/2) | 85 | or | 2s2.2p5.3d | 1P* | 72 |

| Ti 12 | 2p5.(2P*<3/2>).3s.3p.(3P*<2>) | 4D | 7/2 | | (3/2,2) | | or | 2p5.3s.(3P*).3p | 4D | |

| Ti 12 | 2p5.(2P*<3/2>).3s.3d.(3D*<3>) | 4F* | 9/2 | | (3/2,3) | | or | 2p5.3s.(3P*).3d | 4F* | |

| V 19 | 2s.2p2 | 2S | 1/2 | 716370 | 2P | 51 | | 2s.2p2 | 2S | 48 |

| V 19 | 2s.2p2 | 2P | 1/2 | 788850 | 2S | 50 | | 2s.2p2 | 2P | 49 |

+-------+-------------------------------+------------+-------+----------+------------+------+------+-----------------------+------------+-------+

1.1.3. Energy value changes in Monograph 8

There were only two energy value changes made to the printed version of Monograph 8. The Co XIII 3s²3p²4d ²D J=5/2 level was listed with two different energies in Monograph 8, 1464400 and 1464500 cm^-1. The latter value was adopted because it fits both observed lines at 70.68 and 72.66 Å better. The second case is in Mo VII. The 4p⁵(²P^o_1/2)6s (1/2,1/2)^o J=1 level with energy 732563 cm^-1 was also present as [1/2]* J = 1 and energy 732582.5 cm^-1. The latter energy and Jl term designation 2[1/2]^o are adopted here.

In the beginning of the conversion process, several tens of corrections were made to the pre-print version of Monograph 8, so that the more accurate energy value from ASD would remain there. However, most of these corrections seem to have been taken care of in the printed version of Monograph 8, so it was decided to just use the revised energy values from the printed Monograph 8. It should be noted that there are 121 energy values that seem to be rounded off in Monograph 8 to the nearest tens, hundreds, or thousands. These levels are listed below.

+-------+--------------------+------+-------+-----------+-----------+

+-------+--------------------+------+-------+-----------+-----------+

| Co 14 | 3s2.3p.4d | 1F* | 3 | 1837200 | 1837000 |

| Co 16 | 3s.4s | 3S | 1 | 1969470 | 1969500 |

| Co 26 | 1s.3s | 3S | 1 | 68559570 | 68560000 |

| Cr 13 | 3s.5d | 3D | 3 | 2076540 | 2076500 |

| Cr 14 | 2p6.3p | 2P* | 1/2 | 242688 | 242690 |

| Cr 18 | 2s2.2p3 | 2D* | 5/2 | 150814 | 150810 |

| Cr 19 | 2s2.2p2 | 1D | 2 | 184597 | 184600 |

| Cr 19 | 2s.2p3 | 1D* | 2 | 976220 | 976000 |

| Cr 23 | 1s.4s | 3S | 1 | 56658460 | 56658500 |

| Cr 23 | 1s.4p | 3P* | 0 | 56682840 | 56683000 |

| Cr 24 | 2s | 2S | 1/2 | 47723241 | 47723240 |

| Cr 24 | 2p | 2P* | 3/2 | 47843596 | 47843600 |

| Cr 24 | 3p | 2P* | 1/2 | 56598064 | 56598060 |

| Cr 24 | 3d | 2D | 5/2 | 56646759 | 56646760 |

| Cr 24 | 4d | 2D | 5/2 | 59720933 | 59720930 |

| Cr 24 | 5f | 2F* | 7/2 | 61145982 | 61145980 |

| Cu 11 | 3p5.(2P*).3d2.(3F) | 2F* | 5/2 | 669098 | 669100 |

| Cu 11 | 3p5.(2P*).3d2.(3P) | 2P* | 3/2 | 739173 | 739200 |

| Cu 23 | 2s2.2p3 | 2P* | 1/2 | 327860 | 327900 |

| Cu 28 | 1s.3s | 3S | 1 | 79453170 | 79453200 |

| Cu 28 | 1s.3p | 3P* | 0 | 79526970 | 79527000 |

| Cu 28 | 1s.3s | 1S | 0 | 79530270 | 79530300 |

| Cu 28 | 1s.3p | 3P* | 2 | 79591180 | 79591200 |

| Cu 28 | 1s.3d | 3D | 2 | 79629680 | 79629700 |

| Cu 28 | 1s.3d | 3D | 1 | 79630780 | 79630800 |

| Cu 28 | 1s.3p | 1P* | 1 | 79634280 | 79634300 |

| Cu 28 | 1s.3d | 3D | 3 | 79651350 | 79651400 |

| Cu 29 | 2p | 2P* | 3/2 | 70162455 | 70162460 |

| Cu 29 | 3d | 2D | 3/2 | 83006306 | 83006310 |

| Cu 29 | 3d | 2D | 5/2 | 83032077 | 83032080 |

| Cu 29 | 4p | 2P* | 3/2 | 87510822 | 87510820 |

| Cu 29 | 4d | 2D | 5/2 | 87521643 | 87521640 |

| Cu 29 | 4f | 2F* | 7/2 | 87527037 | 87527040 |

| Cu 29 | 5d | 2D | 5/2 | 89601488 | 89601490 |

| Cu 29 | 5f | 2F* | 7/2 | 89604251 | 89604250 |

| Fe 15 | 3p2 | 1D | 2 | 559590 | 559600 |

| Fe 25 | 1s.3p | 3P* | 1 | 63490690 | 63490700 |

| Fe 25 | 1s.4p | 3P* | 0 | 66873940 | 66873900 |

| Fe 26 | 2s | 2S | 1/2 | 56075896 | 56075900 |

| Fe 26 | 2p | 2P* | 3/2 | 56242454 | 56242450 |

| Fe 26 | 3d | 2D | 5/2 | 66578923 | 66578900 |

| Fe 26 | 4d | 2D | 5/2 | 70187128 | 70187100 |

| Kr 6 | 4s2.4p | 2P* | 3/2 | 8108 | 8110 |

| Kr 6 | 4s2.4d | 2D | 5/2 | 223037 | 223040 |

| Kr 36 | 2p | 2P* | 3/2 | 108956893 | 108956890 |

| Kr 36 | 3d | 2D | 3/2 | 128771408 | 128771410 |

| Kr 36 | 3d | 2D | 5/2 | 128832867 | 128832870 |

| Kr 36 | 4d | 2D | 5/2 | 135754189 | 135754190 |

| Kr 36 | 4f | 2F* | 7/2 | 135767024 | 135767020 |

| Kr 36 | 5p | 2P* | 3/2 | 138948877 | 138948880 |

| Kr 36 | 5d | 2D | 5/2 | 138962096 | 138962100 |

| Kr 36 | 5f | 2F* | 7/2 | 138968672 | 138968670 |

| Mn 12 | 3s2.3p.3d | 3D* | 1 | 469910 | 469900 |

| Mn 14 | 3s.4s | 3S | 1 | 1568920 | 1568900 |

| Mn 14 | 3s.4p | 1P* | 1 | 1685630 | 1685600 |

| Mn 14 | 3s.4d | 3D | 1 | 1818070 | 1818000 |

| Mn 14 | 3s.4d | 3D | 2 | 1818540 | 1818500 |

| Mn 14 | 3s.4d | 3D | 3 | 1819460 | 1819500 |

| Mn 14 | 3s.4f | 3F* | 4 | 1888210 | 1888200 |

| Mn 14 | 3s.4f | 1F* | 3 | 1901260 | 1901300 |

| Mn 15 | 2p6.5f | 2F* | 5/2 | 2519100 | 2519000 |

| Mn 24 | 1s.3p | 3P* | 0 | 58550250 | 58550200 |

| Mn 24 | 1s.4p | 3P* | 2 | 61684720 | 61685000 |

| Mn 25 | 2s | 2S | 1/2 | 51813492 | 51813490 |

| Mn 25 | 2p | 2P* | 3/2 | 51955528 | 51955530 |

| Mn 25 | 3p | 2P* | 1/2 | 61452412 | 61452400 |

| Mn 25 | 3d | 2D | 5/2 | 61509824 | 61509820 |

| Mn 25 | 5f | 2F* | 7/2 | 66392206 | 66392200 |

| Mo 27 | 3s2.3p4 | 1S | 0 | 427260 | 427000 |

| Mo 31 | 3s.3p | 3P* | 1 | 525028 | 525030 |

| Mo 31 | 3s.4f | 3F* | 4 | 7281800 | 7282000 |

| Mo 41 | 1s.2s | 3S | 1 | 143972042 | 143972040 |

| Mo 41 | 1s.2p | 3P* | 0 | 144418218 | 144418220 |

| Mo 41 | 1s.2p | 3P* | 1 | 144429731 | 144429730 |

| Mo 41 | 1s.2s | 1S | 0 | 144441297 | 144441300 |

| Mo 41 | 1s.2p | 3P* | 2 | 145466036 | 145466040 |

| Mo 41 | 1s.2p | 1P* | 1 | 145685798 | 145685800 |

| Mo 41 | 1s.3p | 3P* | 0 | 171025507 | 171025510 |

| Mo 41 | 1s.3s | 1S | 0 | 171027461 | 171027460 |

| Mo 41 | 1s.3p | 3P* | 1 | 171028623 | 171028620 |

| Mo 41 | 1s.3p | 3P* | 2 | 171337276 | 171337280 |

| Mo 41 | 1s.3p | 1P* | 1 | 171398128 | 171398130 |

| Mo 41 | 1s.4s | 3S | 1 | 180230481 | 180230480 |

| Mo 41 | 1s.4p | 3P* | 0 | 180280592 | 180280590 |

| Mo 41 | 1s.4s | 1S | 0 | 180280817 | 180280820 |

| Mo 41 | 1s.4p | 3P* | 1 | 180281884 | 180281880 |

| Mo 41 | 1s.4p | 3P* | 2 | 180411971 | 180411970 |

| Mo 41 | 1s.4p | 1P* | 1 | 180437009 | 180437010 |

| Mo 41 | 1s.5s | 3S | 1 | 184517023 | 184517020 |

| Mo 41 | 1s.5s | 1S | 0 | 184542596 | 184542600 |

| Mo 41 | 1s.5p | 3P* | 2 | 184609428 | 184609430 |

| Mo 41 | 1s.5p | 1P* | 1 | 184622089 | 184622090 |

| Ni 17 | 3s.4f | 3F* | 3 | 2585400 | 2585000 |

| Ni 24 | 2p3 | 2P* | 3/2 | 1872900 | 1873000 |

| Ni 27 | 1s.3s | 3S | 1 | 73903340 | 73903000 |

| Ni 27 | 1s.5s | 3S | 1 | 79740940 | 79741000 |

| Ni 28 | 3s | 2S | 1/2 | 77250120 | 77250100 |

| Ti 10 | 3s.3p2 | 2P | 3/2 | 285218 | 285220 |

| Ti 12 | 2p6.4d | 2D | 3/2 | 1321430 | 1321400 |

| Ti 12 | 2p6.4f | 2F* | 7/2 | 1360470 | 1360500 |

| Ti 12 | 2p6.8d | 2D | 5/2 | 2098880 | 2098900 |

| Ti 12 | 2p6.8d | 2D | 3/2 | 2098880 | 2098900 |

| Ti 14 | 2s2.2p4.(1S).3d | 2D | 3/2 | 4693800 | 4694000 |

| Ti 22 | 2s | 2S | 1/2 | 40056747 | 40056750 |

| Ti 22 | 2p | 2P* | 3/2 | 40141335 | 40141340 |

| Ti 22 | 3p | 2P* | 3/2 | 47526701 | 47526700 |

| Ti 22 | 3d | 2D | 5/2 | 47535163 | 47535160 |

| Ti 22 | 4d | 2D | 5/2 | 50118110 | 50118100 |

| Ti 22 | 5f | 2F* | 7/2 | 51315161 | 51315160 |

| V 12 | 3s.4d | 3D | 2 | 1424820 | 1425000 |

| V 12 | 3s.4f | 3F* | 2 | 1480560 | 1480600 |

| V 12 | 3p.4d | 3D* | 2 | 1657900 | 1658000 |

| V 12 | 3s.5d | 3D | 3 | 1818900 | 1819000 |

| V 12 | 3s.6f | 3F* | 4 | 2041900 | 2042000 |

| V 23 | 3p | 2P* | 1/2 | 51947814 | 51947810 |

| V 23 | 3s | 2S | 1/2 | 51948737 | 51948740 |

| V 23 | 3d | 2D | 3/2 | 51978665 | 51978660 |

| V 23 | 3d | 2D | 5/2 | 51988832 | 51988830 |

| V 23 | 4d | 2D | 5/2 | 54812044 | 54812040 |

| V 23 | 5d | 2D | 5/2 | 56119506 | 56119500 |

| V 23 | 5f | 2F* | 7/2 | 56120597 | 56120600 |

+-------+--------------------+------+-------+-----------+-----------+

1.1.4. J-value changes in Monograph 8

Several unresolved terms have been split into individual J-components in Monograph 8. Any observed lines involving these unresolved terms have also been split into individual multiplet lines.

+---------+---------------+---------------------+----------+-----------+-------+-------

+---------+---------------+---------------------+----------+-----------+-------+-------

| Ni | 17 | 3s.5d | 3D | 3272200 | 1 | 1,2

| Ni | 17 | 3s.5d | 3D | 3272200 | 2 | 1,2

| Ni | 17 | 3s.5f | 3F* | 3312800 | 2 | 2,3,4

| Ni | 17 | 3s.5f | 3F* | 3312800 | 3 | 2,3,4

| Ni | 17 | 3s.5f | 3F* | 3312800 | 4 | 2,3,4

| Ni | 21 | 2s2.2p3.(2D*).3s | 3D* | 8146000 | 1 | 1,2

| Ni | 25 | 1s2.2p.3d | 3P* | 11456000 | 1 | 1,2

| Ti | 4 | 3p6.6h | 2H* | 300158.76 | 9/2 |

| Ti | 4 | 3p6.6h | 2H* | 300158.76 | 11/2 |

| Ti | 4 | 3p6.7h | 2H* | 313110.72 | 9/2 |

| Ti | 4 | 3p6.7i | 2I | 313130.66 | 11/2 |

| Ti | 4 | 3p6.7i | 2I | 313130.66 | 13/2 |

| Ti | 4 | 3p6.8i | 2I | 321531.3 | 11/2 |

| Ti | 4 | 3p6.8i | 2I | 321531.3 | 13/2 |

| V | 5 | 3p6.6h | 2H* | 450247.99 | 9/2 |

| V | 5 | 3p6.7h | 2H* | 470488.77 | 11/2 |

| V | 5 | 3p6.7h | 2H* | 470488.77 | 9/2 |

| V | 5 | 3p6.7i | 2I | 470524.11 | 11/2 |

| V | 5 | 3p6.7i | 2I | 470524.11 | 13/2 |

| V | 5 | 3p6.8i | 2I | 483650.82 | 11/2 |

+---------+---------------+---------------------+----------+-----------+-------+-------

1.2. Line changes in Monograph 8

1.2.1. Line identification changes in Monograph 8

The lines of Cr XXII 81.599 Å (1s²4p ²P^o_1/2 - 1s²5d ²D_3/2 [10527820] – [11753320]) and 82.238 Å (1s²4p ²P^o_3/2 - 1s²5d ²D_5/2 [10539180] – [11755160]) were listed without configuration and term designations in Monograph 8. This was corrected.

The Kr VIII line at 6056.3 Å was listed in Monograph 8 as 3d¹⁰9l ²L - 3d¹⁰10m ²M^o transition. This was a misprint. After discussion, the classification was changed to 3d¹⁰9k ²K^o - 3d¹⁰10l ²L. The published wavelength of the 3d¹⁰9l ²L - 3d¹⁰10m ²M^o line is 6065.8 +/- 0.8 Å while Monograph 8 lists it as 6065.5 Å, however, it was decided not to change the wavelength. Monograph 8 cites the NIST Special Publication 850 (1993), which is proceedings of a conference, while the final paper of the same authors was published next year (E. Jacquet, P. Boduch, M. Chantepie, M. Druetta, D. Hennecart, X. Husson, D. Lecler, F. Martin-Brunetiere, R. E. Olson, J. Pascale, and M. Wilson, Phys. Scripta 49, 154 (1994)). If it would be decided to change this wavelength, one would have to go through the whole list of Kr VIII wavelengths in Monograph 8, to change them, and to replace the reference.

1.2.2. Wavelength changes in Monograph 8

Transition 4p⁶5g ²G – 4p⁶6h ²H^o of Mo VI was listed in Monograph 8 with wavelength 2003.14 Å. The calculated vacuum wavelengths of the 5g ²G_7/2- 6h ²H^o and 5g ²G_9/2 - 6h ²H^o transitions are 2003.10 and 2003.18 Å, respectively. Thus, the listed wavelength is in vacuum while, according to the general convention, it should be given in air. The observed wavelength was changed to 2002.49 Å.

It should be noted that ASD has separate columns for observed, calculated (Ritz), and vacuum (also Ritz?) wavelengths, while Monograph 8 has only one printed value for the wavelength. This value was stored as observed wavelength if the comment (superscript to the wavelength) in Monograph 8 was empty or ‘S’ or ‘L’ or ‘T’. If this comment was ‘P’ or ‘C’, the given wavelength was stored in the calculated-wavelength column of ASD, and the observed wavelength column was left blank.

1.2.3. Transition probability changes in Monograph 8

For 92 lines listed in Monograph 8 without transition probability data, the non-empty transition probability data listed in ASD were retained. The affected spectra and number of such cases per spectrum are listed below.

+-------+-----+

| spect | cnt |

+-------+-----+

| Co 17 | 2 |

| Co 20 | 1 |

| Cr 14 | 6 |

| Cr 22 | 6 |

| Fe 13 | 1 |

| Fe 17 | 1 |

| Fe 20 | 1 |

| Fe 24 | 4 |

| Mn 12 | 1 |

| Mn 15 | 6 |

| Mn 23 | 2 |

| Ni 18 | 2 |

| Ti 3 | 10 |

| Ti 4 | 3 |

| Ti 12 | 6 |

| Ti 15 | 1 |

| Ti 17 | 1 |

| Ti 18 | 1 |

| Ti 20 | 18 |

| V 4 | 1 |

| V 13 | 6 |

| V 21 | 12 |

+-------+-----+

1.2.4. Observed Intensity changes in Monograph 8

For 392 lines listed in Monograph 8 with empty observed intensity, intensity ‘0’ that was stored in the pre-print (Oracle) version of Monograph 8 for these lines was retained. The zeros were cited from the original publications but later the authors of Monograph 8 decided to omit them. It is better to keep the original intensity values because they keep some information about the character of observed lines.

There were also 48 cases when the intensity given in Monograph 8 was incorrect compared with the original publications cited in Monograph 8. They were corrected by comparing with the original papers. These cases are listed below.

+-------+---------+------------------------------------------------------------------------+-------+------+---------+

+-------+---------+------------------------------------------------------------------------+-------+------+---------+

| Co 8 | 101.904 | 3p6.3d2 3F 2 - 3p6.3d.5f 3G* 3 | 3 | | 2 |

| Co 16 | 310.324 | 3s.3d 1D 2 - 3p.3d 1F* 3 | 440 | | 26 |

| Co 19 | 12.942 | 2s2.2p5 2P* 3/2 - 2s2.2p4.(1D).3d 2P 3/2 | 10 | 9 | 44,51 |

| Co 19 | 13.084 | 2s2.2p5 2P* 1/2 - 2s2.2p4.(1D).3d 2P 1/2 | 12 | 10 | 44,51 |

| Co 24 | 9.974 | 1s2.2s.2p 3P* 1 - 1s2.2p.3p 3P 2 | 1 | | 43 |

| Co 24 | 10.503 | 1s2.2s.2p 1P* 1 - 1s2.2p.3p 1P 1 | 2 | | 43 |

| Fe 17 | 280.20 | 2s2.2p5.3p 1D 2 - 2s2.2p5.3d 1F* 3 | 85 | | 80 |

| Fe 18 | 14.203 | 2s2.2p5 2P* 3/2 - 2s2.2p4.(1D).3d 2P 3/2 | 60 | | 84 |

| Kr 23 | 112.586 | 3s2.3p2 3P 0 - 3s2.3p.3d 3D* 1 | 5bl | 50 | 34 |

| Kr 23 | 112.586 | 3s2.3p2 3P 1 - 3s2.3p.3d 3P* 1 | 5bl | 5 | 34 |

| Kr 23 | 114.921 | 3s2.3p2 3P 1 - 3s2.3p.3d 1D* 2 | 10 | 8 | 34 |

| Kr 23 | 116.797 | 3s2.3p2 3P 2 - 3s2.3p.3d 3D* 3 | 50 | 10 | 34 |

| Kr 23 | 118.468 | 3s2.3p2 3P 2 - 3s2.3p.3d 1D* 2 | 8 | 5 | 34 |

| Kr 25 | 133.24 | 3p.3d 3F* 3 - 3d2 3F 3 | 10 | bl | 40 |

| Kr 25 | 143.90 | 3s.3p 3P* 2 - 3s.3d 3D 2 | 10bl | bl | 40 |

| Kr 25 | 143.90 | 3p.3d 3F* 4 - 3d2 3F 4 | 10bl | 10 | 40 |

| Kr 25 | 146.15 | 3p2 3P 2 - 3p.3d 3P* 2 | 7bl | 7 | 40 |

| Kr 25 | 146.15 | 3p2 1S 0 - 3p.3d 1P* 1 | 7bl | bl | 40 |

| Kr 25 | 168.55 | 3s.3d 3D 1 - 3p.3d 3P* 1 | 18bl | bl | 40 |

| Kr 25 | 168.55 | 3p.3d 1F* 3 - 3d2 1G 4 | 18bl | bl | 40 |

| Kr 25 | 168.9 | 3s.3d 3D 1 - 3p.3d 3P* 0 | 8bl | bl | 40 |

| Kr 25 | 168.9 | 3s.3d 3D 2 - 3p.3d 3P* 2 | 8bl | bl | 40 |

| Kr 25 | 192.92 | 3s.3d 3D 3 - 3p.3d 3F* 4 | 15bl | bl | 40 |

| Kr 25 | 192.92 | 3s.3p 3P* 1 - 3p2 3P 0 | 15bl | bl | 40 |

| Kr 25 | 217.03 | 3s.3d 3D 2 - 3p.3d 3F* 3 | 5 | 6 | 40 |

| Mo 9 | 94.008 | 4s2.4p4 1D 2 - 4s2.4p3.(2P*<3/2>).7s (3/2,1/2)* 1 | 6w | 6 | 17 |

| Mo 9 | 94.120 | 4s2.4p4 3P 1 - 4s2.4p3.(2P*<1/2>).7s (1/2,1/2)* 1 | 5w | 5 | 17 |

| Mo 9 | 97.416 | 4s2.4p4 1S 0 - 4s2.4p3.(2P*<3/2>).7s (3/2,1/2)* 1 | 1 | 4 | 17 |

| Mo 9 | 98.077 | 4s2.4p4 1D 2 - 4s2.4p3.(2D*<3/2>).7s (3/2,1/2)* 2 | 1w | 1 | 17 |

| Mo 9 | 98.087 | 4s2.4p4 3P 1 - 4s2.4p3.(2D*).6d 3P* 1 | 1w | 1 | 17 |

| Mo 9 | 98.097 | 4s2.4p4 1D 2 - 4s2.4p3.(2D*<3/2>).7s (3/2,1/2)* 1 | 1w | 1 | 17 |

| Mo 9 | 100.246 | 4s2.4p4 3P 1 - 4s2.4p3.(2P*).6d 3P* 1 | 4w | 4 | 17 |

| Mo 9 | 100.246 | 4s2.4p4 1D 2 - 4s2.4p3.(2D*).6d 3P* 2 | 4w | 4 | 17 |

| Mo 9 | 110.391 | 4s2.4p4 3P 2 - 4s2.4p3.(2D*<3/2>).6s (3/2,1/2)* 2 | 8w | 8 | 17 |

| Mo 9 | 112.916 | 4s2.4p4 3P 1 - 4s2.4p3.(2D*<3/2>).6s (3/2,1/2)* 1 | 12w | 12 | 17 |

| Mo 9 | 114.935 | 4s2.4p4 3P 0 - 4s2.4p3.(2P*).5d 1P* 1 | 4w | 4 | 17 |

| Mo 9 | 117.814 | 4s2.4p4 3P 2 - 4s2.4p3.(2D*).5d 3P* 1 | 5w | 5 | 17 |

| Mo 9 | 117.814 | 4s2.4p4 3P 0 - 4s2.4p3.(4S*).5d 3D* 1 | 5w | 5 | 17 |

| Mo 9 | 119.114 | 4s2.4p4 3P 2 - 4s2.4p3.(2P*).5d 3D* 3 | 10bl | 10 | 17 |

| Mo 9 | 123.178 | 4s2.4p4 1D 2 - 4s2.4p3.(4S*).5d 3D* 3 | 6w | 6 | 17 |

| Ni 9 | 140.917 | 3p6.3d2 3F 3 - 3p5.(2P*).3d3.(4F) 3D* 3 | 4 | | 3 |

| Ni 17 | 226.093 | 3p2 1D 2 - 3p.3d 1D* 2 | 170bl | 170 | 37,37 |

| Ni 17 | 226.093 | 3p.3d 3D* 1 - 3d2 3F 2 | 170bl | b | 41,37 |

| Ni 19 | 234.90 | 2s2.2p5.(2P*<1/2>).3p (1/2,1/2) 1 - 2s2.2p5.(2P*<1/2>).3d (1/2,3/2)* 2 | bl | | 61 |

| Ni 19 | 250.39 | 2s2.2p5.(2P*<1/2>).3p (1/2,3/2) 2 - 2s2.2p5.(2P*<1/2>).3d (1/2,5/2)* 3 | bl | | 61 |

| V 5 | 2318.95 | 3p6.4d 2D 3/2 - 3p5.(2P*).3d2.(1D) 2F* 5/2 | 20bl | 20 | 8 |

| V 10 | 255.54 | 3s2.3p2 3P 2 - 3s2.3p.3d 3D* 2 | bl | | 30 |

| V 20 | 11.523 | 1s2.2p2 3P 2 - 1s2.2p.4d 3F* 3 | 4 | | 80 |

+-------+---------+------------------------------------------------------------------------+-------+------+---------+

1.2.5. Lines deleted from Monograph 8

The lines listed in the table below were deleted from the linelist of Monograph 8 because the corresponding unresolved upper or lower levels were split into individual J-components. In all these cases, two or more lines were added in place of each deleted line. The added lines are listed in the following section.

Apart from the term splitting, several lines were deleted because they were duplicated in Monograph 8. The Ti XII line at 127.84 Å (2p⁶4d ²D - 2p⁶8f ²F^o) was deleted because its multiplet components were already present there with calculated wavelengths 127.91 and 127.83 Å. The observed wavelength 127.84 Å and reference to the paper denoted as #36 in Monograph 8 was added to these multiplet lines. The same procedure was done for Ti XII lines at 169.81 Å (2p⁶4d ²D - 2p⁶6f ²F^o), 253.07 Å (2p⁶4d ²D - 2p⁶5f ²F^o), and 468.78 Å (2p⁶5d ²D - 2p⁶6f ²F^o).

Lines deleted from Monograph 8

+-------+----------+--------+--------+------------------------------------------------------------------+-----------------------+

+-------+----------+--------+--------+------------------------------------------------------------------+-----------------------+

| Kr 8 | 1157.60 | 4 | | 3d10.5g 2G - 3d10.6h 2H* | 733095.6 - 819482.0 |

| Kr 8 | 1916.7 | | | 3d10.6g 2G - 3d10.7f 2F* | 815450 - 867623 |

| Mo 6 | 1019.76 | 2 | | 4p6.(1S).5g 2G - 4p6.(1S).8h 2H* | 395185.7 - 493249.5 |

| Mo 6 | 1264.04 | 15 | | 4p6.(1S).5g 2G - 4p6.(1S).7h 2H* | 395185.7 - 474299.7 |

| Mo 6 | 2003.14 | 50 | | 4p6.(1S).5g 2G - 4p6.(1S).6h 2H* | 395185.7 - 445107.3 |

| Mo 6 | 3122.43 | 10 | | 4p6.(1S).7h 2H* - 4p6.(1S).9i 2I | 474299.7 - 506316.7? |

| Mo 6 | 5247.45 | 35 | | 4p6.(1S).7h 2H* - 4p6.(1S).8i 2I | 474299.7 - 493351.3 |

| Ni 17 | 33.249 | 2 | | 3s.3p 3P* 0 - 3s.5d 3D 1,2 | 264431 - 3272200 |

| Ni 17 | 33.340 | 1 | | 3s.3p 3P* 1 - 3s.5d 3D 1,2 | 272634 - 3272200 |

| Ni 17 | 39.346 | 1 | | 3s.3d 3D 1 - 3s.5f 3F* 2,3,4 | 771268 - 3312800 |

| Ni 17 | 39.373 | 3 | | 3s.3d 3D 2 - 3s.5f 3F* 2,3,4 | 772953 - 3312800 |

| Ni 17 | 39.415 | 2 | | 3s.3d 3D 3 - 3s.5f 3F* 2,3,4 | 775567 - 3312800 |

| Ni 20 | 9.497 | | | 2s2.2p5 2P* 3/2 - 2s2.2p4.(3P).4d 4F 3/2,5/2 | 0 - 10530000 |

| Ni 20 | 9.558 | | | 2s2.2p5 2P* 3/2 - 2s2.2p4.(3P).4d 2D 3/2,5/2 | 0 - 10462000 |

| Ni 21 | 12.277 | | | 2s2.2p4 3P 2 - 2s2.2p3.(2D*).3s 3D* 1,2 | 0 - 8146000 |

| Ni 21 | 12.472 | | 1.8+12 | 2s2.2p4 3P 1 - 2s2.2p3.(2D*).3s 3D* 1,2 | 128290 - 8146000 |

| Ni 25 | 9.707 | | 1.8+13 | 2p2 3P 1 - 2p.3d 3P* 1,2 | 1154300 - 11456000 |

| Ni 25 | 9.759 | | 2.3+13 | 2p2 3P 2 - 2p.3d 3P* 1,2 | 1207800 - 11456000 |

| Ti 3 | 4327.62 | 7 | | 3d.4f 1D* 2 - 3d.(2D<3/2>).5g [5/2] | 159123.78 - 182224.9 |

| Ti 3 | 5121.31 | 2 | | 3d.(2D<5/2>).5g [9/2] - 3d.(2D<5/2>).7h [11/2]* | 182404.4 - 201926.0 |

| Ti 3 | 5130.67 | 2 | | 3d.(2D<3/2>).5g [7/2] - 3d.(2D<3/2>).7h [9/2]* | 182068.3 - 201553.5 |

| Ti 3 | 5136.66 | 2 | | 3d.(2D<5/2>).5g [7/2] - 3d.(2D<5/2>).7h [9/2]* | 182473.9 - 201937.4 |

| Ti 3 | 5161.19 | 1 | | 3d.(2D<5/2>).5g [5/2] - 3d.(2D<5/2>).7h [7/2]* | 182587.3 - 201958.3 |

| Ti 4 | 4618.114 | 15 | | 3p6.5g 2G - 3p6.6h 2H* | 278510.93 - 300158.76 |

| Ti 4 | 4677.58 | 3 | | 3p6.6h 2H* - 3p6.8i 2I | 300158.76 - 321531.3 |

| Ti 4 | 7652.12 | 5 | | 3p6.6g 2G - 3p6.7h 2H* | 300046.05 - 313110.72 |

| Ti 4 | 7706.85 | 8 | | 3p6.6h 2H* - 3p6.7i 2I | 300158.76 - 313130.66 |

| Ti 12 | 127.84 | | | 2p6.4d 2D - 2p6.8f 2F* | 1321640 - 2103660 |

| Ti 12 | 169.81 | | | 2p6.4d 2D - 2p6.6f 2F* | 1321640 - 1910650 |

| Ti 12 | 181.28 | | | 2p6.4f 2F* - 2p6.6g 2G | 1360430 - 1911900 |

| Ti 12 | 253.07 | | | 2p6.4d 2D - 2p6.5f 2F* | 1321640 - 1716830 |

| Ti 12 | 258.24 | | | 2p6.5f 2F* - 2p6.8g 2G | 1716830 - 2104100 |

| Ti 12 | 279.03 | | | 2p6.4f 2F* - 2p6.5g 2G | 1360430 - 1718770 |

| Ti 12 | 320.94 | | | 2p6.5f 2F* - 2p6.7g 2G | 1716830 - 2028360 |

| Ti 12 | 468.78 | | | 2p6.5d 2D - 2p6.6f 2F* | 1697300 - 1910650 |

| Ti 12 | 512.64 | | | 2p6.5f 2F* - 2p6.6g 2G | 1716830 - 1911900 |

| Ti 12 | 670.13 | | | 2p6.6p 2P* 3/2 - 2p6.7d 2D | 1871440 - 2020670 |

| Ti 12 | 780.37 | | | 2p6.6d 2D - 2p6.7f 2F* | 1899530 - 2027670 |

| Ti 12 | 849.54 | | | 2p6.6f 2F* - 2p6.7g 2G | 1910650 - 2028360 |

| Ti 12 | 961.41 | | | 2p6.6d 2D - 2p6.7p 2P* | 1899530 - 2003550 |

| Ti 12 | 1308.42 | | | 2p6.7f 2F* - 2p6.8g 2G | 2027670 - 2104100 |

| V 5 | 4375.1 | | | 3p6.7f 2F* - 3p6.9g 2G | 469714 - 492564 |

| V 5 | 4484.8 | | | 3p6.7g 2G - 3p6.9h 2H* | 470333.55 - 492625 |

| V 5 | 4510.4 | | | 3p6.7h 2H* - 3p6.9i 2I | 470488.77 - 492653 |

| V 5 | 4515.9 | | | 3p6.7i 2I - 3p6.9k 2K* | 470524.11 - 492662 |

| V 5 | 4885.299 | 7 | | 3p6.6g 2G - 3p6.7h 2H* | 450024.87 - 470488.77 |

| V 5 | 4930.533 | 15 | | 3p6.6h 2H* - 3p6.7i 2I | 450247.99 - 470524.11 |

| V 5 | 4976.8 | | | 3p6.6h 2H* - 3p6.7g 2G | 450247.99 - 470333.55 |

| V 5 | 5080.0 | | | 3p6.6g 2G - 3p6.7f 2F* | 450024.87 - 469714 |

| V 5 | 7595.511 | 3 | | 3p6.7h 2H* - 3p6.8i 2I | 470488.77 - 483650.82 |

+-------+----------+--------+--------+------------------------------------------------------------------+-----------------------+

1.2.6. Lines added to Monograph 8 line list

The lines listed below were added to the line list of Monograph 8 as a replacement for the deleted lines listed above.

Lines added to Monograph 8 line list

+-------+----------+--------+---------+---------------------------------------------------------------+-----------------------+

+-------+----------+--------+---------+---------------------------------------------------------------+-----------------------+

| Kr 8 | 1157.60 | | | 3d10.5g 2G 7/2 - 3d10.6h 2H* | 733086.4 - 819482.0 |

| Kr 8 | 1157.60 | | | 3d10.5g 2G 9/2 - 3d10.6h 2H* | 733104.8 - 819482.0 |

| Kr 8 | 1916.7 | | | 3d10.6g 2G - 3d10.7f 2F* 5/2 | 815450 - 867633 |

| Kr 8 | 1916.7 | | | 3d10.6g 2G - 3d10.7f 2F* 7/2 | 815450 - 867613 |

| Mo 6 | 1019.76 | 2* | | 4p6.5g 2G 7/2 - 4p6.8h 2H* 9/2 | 395184..6 - 493249.5 |

| Mo 6 | 1019.76 | 2* | | 4p6.5g 2G 9/2 - 4p6.8h 2H* 11/2 | 395186.7 - 493249.5 |

| Mo 6 | 1264.04 | 15* | | 4p6.5g 2G 7/2 - 4p6.7h 2H* 9/2 | 395184.6 - 474299.7 |

| Mo 6 | 1264.04 | 15* | | 4p6.5g 2G 9/2 - 4p6.7h 2H* 11/2 | 395186.7 - 474299.7 |

| Mo 6 | 2002.49 | 50* | | 4p6.5g 2G 7/2 - 4p6.6h 2H* | 395184.6 - 445107.3 |

| Mo 6 | 2002.49 | 50* | | 4p6.5g 2G 9/2 - 4p6.6h 2H* | 395186.7 - 445107.3 |

| Mo 6 | 3122.43 | 10* | | 4p6.7h 2H* 9/2 - 4p6.9i 2I | 474299.7 - 506316.7? |

| Mo 6 | 3122.43 | 10* | | 4p6.7h 2H* 11/2 - 4p6.9i 2I | 474299.7 - 506316.7? |

| Mo 6 | 5247.45 | 35* | | 4p6.7h 2H* 9/2 - 4p6.8i 2I | 474299.7 - 493351.3 |

| Mo 6 | 5247.45 | 35* | | 4p6.7h 2H* 11/2 - 4p6.8i 2 | 474299.7 - 493351.3 |

| Ni 17 | 33.249 | 2* | | 3s.3p 3P* 0 - 3s.5d 3D 1 | 264431 - 3272200 |

| Ni 17 | 33.249 | 2* | | 3s.3p 3P* 0 - 3s.5d 3D 2 | 264431 - 3272200 |

| Ni 17 | 33.340 | 1* | | 3s.3p 3P* 1 - 3s.5d 3D 1 | 272634 - 3272200 |

| Ni 17 | 33.340 | 1* | | 3s.3p 3P* 1 - 3s.5d 3D 2 | 272634 - 3272200 |

| Ni 17 | 39.346 | 1* | | 3s.3d 3D 1 - 3s.5f 3F* 2 | 771268 - 3312800 |

| Ni 17 | 39.346 | 1* | | 3s.3d 3D 1 - 3s.5f 3F* 3 | 771268 - 3312800 |

| Ni 17 | 39.346 | 1* | | 3s.3d 3D 1 - 3s.5f 3F* 4 | 771268 - 3312800 |

| Ni 17 | 39.373 | 3* | | 3s.3d 3D 2 - 3s.5f 3F* 2 | 772953 - 3312800 |

| Ni 17 | 39.373 | 3* | | 3s.3d 3D 2 - 3s.5f 3F* 3 | 772953 - 3312800 |

| Ni 17 | 39.373 | 3* | | 3s.3d 3D 2 - 3s.5f 3F* 4 | 772953 - 3312800 |

| Ni 17 | 39.415 | 2* | | 3s.3d 3D 3 - 3s.5f 3F* 2 | 775567 - 3312800 |

| Ni 17 | 39.415 | 2* | | 3s.3d 3D 3 - 3s.5f 3F* 3 | 775567 - 3312800 |

| Ni 17 | 39.415 | 2* | | 3s.3d 3D 3 - 3s.5f 3F* 4 | 775567 - 3312800 |

| Ni 20 | 9.497 | | | 2s2.2p5 2P* 3/2 - 2s2.2p4.(3P).4d 4F 3/2 | 0 - 10530000 |

| Ni 20 | 9.497 | | | 2s2.2p5 2P* 3/2 - 2s2.2p4.(3P).4d 4F 5/2 | 0 - 10530000 |

| Ni 20 | 9.558 | | | 2s2.2p5 2P* 3/2 - 2s2.2p4.(3P).4d 2D 3/2 | 0 - 10462000 |

| Ni 20 | 9.558 | | | 2s2.2p5 2P* 3/2 - 2s2.2p4.(3P).4d 2D 5/2 | 0 - 10462000 |

| Ni 21 | 12.277 | | | 2s2.2p4 3P 2 - 2s2.2p3.(2D*).3s 3D* 1 | 0 - 8146000 |

| Ni 21 | 12.277 | | | 2s2.2p4 3P 2 - 2s2.2p3.(2D*).3s 3D* 2 | 0 - 8146000 |

| Ni 21 | 12.472 | | 1.8e+12 | 2s2.2p4 3P 1 - 2s2.2p3.(2D*).3s 3D* 1 | 128290 - 8146000 |

| Ni 21 | 12.472 | | | 2s2.2p4 3P 1 - 2s2.2p3.(2D*).3s 3D* 2 | 128290 - 8146000 |

| Ni 25 | 9.707 | | 1.8e+13 | 1s2.2p2 3P 1 - 1s2.2p.3d 3P* 1 | 1154300 - 11456000 |

| Ni 25 | 9.707 | | 2.7e+12 | 1s2.2p2 3P 1 - 1s2.2p.3d 3P* 2 | 1154300 - 11456000 |

| Ni 25 | 9.759 | | 7.5e+12 | 1s2.2p2 3P 2 - 1s2.2p.3d 3P* 1 | 1207800 - 11456000 |

| Ni 25 | 9.759 | | 1.3e+13 | 1s2.2p2 3P 2 - 1s2.2p.3d 3P* 2 | 1207800 - 11456000 |

| Ti 3 | 4327.62 | 7* | | 3p6.3d.4f 1D* 2 - 3p6.3d.(2D<3/2>).5g 2[5/2] 2 | 159123.78 - 182225.09 |

| Ti 3 | 4327.62 | 7* | | 3p6.3d.4f 1D* 2 - 3p6.3d.(2D<3/2>).5g 2[5/2] 3 | 159123.78 - 182224.72 |

| Ti 3 | 5121.31 | 2* | | 3p6.3d.(2D<5/2>).5g 2[9/2] 5 - 3p6.3d.(2D<5/2>).7h 2[11/2]* 6 | 182403.64 - 201926.0 |

| Ti 3 | 5121.31 | 2* | | 3p6.3d.(2D<5/2>).5g 2[9/2] 5 - 3p6.3d.(2D<5/2>).7h 2[11/2]* 5 | 182403.64 - 201926.0 |

| Ti 3 | 5121.31 | 2* | | 3p6.3d.(2D<5/2>).5g 2[9/2] 4 - 3p6.3d.(2D<5/2>).7h 2[11/2]* 5 | 182405.25 - 201926.0 |

| Ti 3 | 5130.67 | 2* | | 3p6.3d.(2D<3/2>).5g 2[7/2] 3 - 3p6.3d.(2D<3/2>).7h 2[9/2]* 4 | 182067.49 - 201553.5 |

| Ti 3 | 5130.67 | 2* | | 3p6.3d.(2D<3/2>).5g 2[7/2] 4 - 3p6.3d.(2D<3/2>).7h 2[9/2]* 4 | 182068.87 - 201553.5 |

| Ti 3 | 5136.66 | 2* | | 3p6.3d.(2D<5/2>).5g 2[7/2] 3 - 3p6.3d.(2D<5/2>).7h 2[9/2]* 4 | 182473.21 - 201937.4 |

| Ti 3 | 5136.66 | 2* | | 3p6.3d.(2D<5/2>).5g 2[7/2] 4 - 3p6.3d.(2D<5/2>).7h 2[9/2]* 4 | 182474.38 - 201937.4 |

| Ti 3 | 5136.66 | 2* | | 3p6.3d.(2D<5/2>).5g 2[7/2] 4 - 3p6.3d.(2D<5/2>).7h 2[9/2]* 5 | 182474.38 - 201937.4 |

| Ti 3 | 5161.19 | 1* | | 3p6.3d.(2D<5/2>).5g 2[5/2] 2 - 3p6.3d.(2D<5/2>).7h 2[7/2]* 3 | 182587.62 - 201958.3 |

| Ti 3 | 5161.19 | 1* | | 3p6.3d.(2D<5/2>).5g 2[5/2] 3 - 3p6.3d.(2D<5/2>).7h 2[7/2]* 4 | 182587.12 - 201958.3 |

| Ti 3 | 5161.19 | 1* | | 3p6.3d.(2D<5/2>).5g 2[5/2] 3 - 3p6.3d.(2D<5/2>).7h 2[7/2]* 3 | 182587.12 - 201958.3 |

| Ti 4 | 4618.114 | 15* | | 3p6.5g 2G 9/2 - 3p6.6h 2H* 9/2 | 278511.23 - 300158.76 |

| Ti 4 | 4618.114 | 15* | | 3p6.5g 2G 7/2 - 3p6.6h 2H* 9/2 | 278510.63 - 300158.76 |

| Ti 4 | 4618.114 | 15* | | 3p6.5g 2G 9/2 - 3p6.6h 2H* 11/2 | 278511.23 - 300158.76 |

| Ti 4 | 4677.58 | 3* | | 3p6.6h 2H* 9/2 - 3p6.8i 2I 11/2 | 300158.76 - 321531.3 |

| Ti 4 | 4677.58 | 3* | | 3p6.6h 2H* 11/2 - 3p6.8i 2I 11/2 | 300158.76 - 321531.3 |

| Ti 4 | 4677.58 | 3* | | 3p6.6h 2H* 11/2 - 3p6.8i 2I 13/2 | 300158.76 - 321531.3 |

| Ti 4 | 7652.12 | 5* | | 3p6.6g 2G 9/2 - 3p6.7h 2H* 9/2 | 300046.2 - 313110.72 |

| Ti 4 | 7652.12 | 5* | | 3p6.6g 2G 7/2 - 3p6.7h 2H* 9/2 | 300045..9 - 313110.72 |

| Ti 4 | 7652.12 | 5* | | 3p6.6g 2G 9/2 - 3p6.7h 2H* 11/2 | 300046.2 - 313110.72 |

| Ti 4 | 7706.85 | 8* | | 3p6.6h 2H* 9/2 - 3p6.7i 2I 11/2 | 300158.76 - 313130.66 |

| Ti 4 | 7706.85 | 8* | | 3p6.6h 2H* 11/2 - 3p6.7i 2I 11/2 | 300158.76 - 313130.66 |

| Ti 4 | 7706.85 | 8* | | 3p6.6h 2H* 11/2 - 3p6.7i 2I 13/2 | 300158.76 - 313130.66 |

| Ti 12 | 181.28 | | | 2p6.4f 2F* 5/2 - 2p6.6g 2G | 1360350 - 1911900 |

| Ti 12 | 181.28 | | | 2p6.4f 2F* 7/2 - 2p6.6g 2G | 1360500 - 1911900 |

| Ti 12 | 258.24 | | | 2p6.5f 2F* 5/2 - 2p6.8g 2G | 1716830 - 2104100 |

| Ti 12 | 258.24 | | | 2p6.5f 2F* 7/2 - 2p6.8g 2G | 1716830 - 2104100 |

| Ti 12 | 279.03 | | | 2p6.4f 2F* 5/2 - 2p6.5g 2G | 1360350 - 1718770 |

| Ti 12 | 279.03 | | | 2p6.4f 2F* 7/2 - 2p6.5g 2G | 1360500 - 1718770 |

| Ti 12 | 320.94 | | | 2p6.5f 2F* 5/2 - 2p6.7g 2G | 1716830 - 2028360 |

| Ti 12 | 320.94 | | | 2p6.5f 2F* 7/2 - 2p6.7g 2G | 1716830 - 2028360 |

| Ti 12 | 512.64 | | | 2p6.5f 2F* 5/2 - 2p6.6g 2G | 1716830 - 1911900 |

| Ti 12 | 512.64 | | | 2p6.5f 2F* 7/2 - 2p6.6g 2G | 1716830 - 1911900 |

| Ti 12 | 670.13 | | | 2p6.6p 2P* 3/2 - 2p6.7d 2D 3/2 | 1871440 - 2020670 |

| Ti 12 | 670.13 | | | 2p6.6p 2P* 3/2 - 2p6.7d 2D 5/2 | 1871440 - 2020670 |

| Ti 12 | 780.37 | | | 2p6.6d 2D 3/2 - 2p6.7f 2F* 5/2 | 1899530 - 2027670 |

| Ti 12 | 780.37 | | | 2p6.6d 2D 5/2 - 2p6.7f 2F* 5/2 | 1899530 - 2027670 |

| Ti 12 | 780.37 | | | 2p6.6d 2D 5/2 - 2p6.7f 2F* 7/2 | 1899530 - 2027670 |

| Ti 12 | 849.54 | | | 2p6.6f 2F* 5/2 - 2p6.7g 2G | 1910650 - 2028360 |

| Ti 12 | 849.54 | | | 2p6.6f 2F* 7/2 - 2p6.7g 2G | 1910650 - 2028360 |

| Ti 12 | 961.41 | | | 2p6.6d 2D 3/2 - 2p6.7p 2P* 1/2 | 1899530 - 2003550 |

| Ti 12 | 961.41 | | | 2p6.6d 2D 3/2 - 2p6.7p 2P* 3/2 | 1899530 - 2003550 |

| Ti 12 | 961.41 | | | 2p6.6d 2D 3/2 - 2p6.7p 2P* 5/2 | 1899530 - 2003550 |

| Ti 12 | 1308.42 | | | 2p6.7f 2F* 5/2 - 2p6.8g 2G | 2027670 - 2104100 |

| Ti 12 | 1308.42 | | | 2p6.7f 2F* 7/2 - 2p6.8g 2G | 2027670 - 2104100 |

| V 5 | 4375.1 | | | 3p6.7f 2F* 5/2 - 3p6.9g 2G | 469706.4 - 492564 |

| V 5 | 4375.1 | | | 3p6.7f 2F* 7/2 - 3p6.9g 2G | 469721 - 492564 |

| V 5 | 4484.8 | | | 3p6.7g 2G 7/2 - 3p6.9h 2H* | 470333.35 - 492625 |

| V 5 | 4484.8 | | | 3p6.7g 2G 9/2 - 3p6.9h 2H* | 470333.75 - 492625 |

| V 5 | 4510.4 | | | 3p6.7h 2H* 9/2 - 3p6.9i 2I | 470488.77 - 492653 |

| V 5 | 4510.4 | | | 3p6.7h 2H* 11/2 - 3p6.9i 2I | 470488.77 - 492653 |

| V 5 | 4515.9 | | | 3p6.7i 2I 11/2 - 3p6.9k 2K* | 470524.11 - 492662 |

| V 5 | 4515.9 | | | 3p6.7i 2I 13/2 - 3p6.9k 2K* | 470524.11 - 492662 |

| V 5 | 4885.299 | 7* | | 3p6.6g 2G 7/2 - 3p6.7h 2H* 9/2 | 450024.54 - 470488.77 |

| V 5 | 4885.299 | 7* | | 3p6.6g 2G 9/2 - 3p6.7h 2H* 9/2 | 450025.20 - 470488.77 |

| V 5 | 4885.299 | 7* | | 3p6.6g 2G 9/2 - 3p6.7h 2H* 11/2 | 450025.20 - 470488.77 |

| V 5 | 4930.533 | 15* | | 3p6.6h 2H* 9/2 - 3p6.7i 2I 11/2 | 450247.99 - 470524.11 |

| V 5 | 4930.533 | 15* | | 3p6.6h 2H* 11/2 - 3p6.7i 2I 11/2 | 450247.99 - 470524.11 |

| V 5 | 4930.533 | 15* | | 3p6.6h 2H* 11/2 - 3p6.7i 2I 13/2 | 450247.99 - 470524.11 |

| V 5 | 4976.8 | | | 3p6.6h 2H* 9/2 - 3p6.7g 2G 9/2 | 450247.99 - 470333.75 |

| V 5 | 4976.8 | | | 3p6.6h 2H* 11/2 - 3p6.7g 2G 9/2 | 450247.99 - 470333.75 |

| V 5 | 4976.8 | | | 3p6.6h 2H* 9/2 - 3p6.7g 2G 7/2 | 450247.99 - 470333.35 |

| V 5 | 5080.0 | | | 3p6.6g 2G 7/2 - 3p6.7f 2F* 7/2 | 450024.54 - 469721 |

| V 5 | 5080.0 | | | 3p6.6g 2G 9/2 - 3p6.7f 2F* 7/2 | 450025.20 - 469721 |

| V 5 | 7595.511 | 3* | | 3p6.7h 2H* 11/2 - 3p6.8i 2I 11/2 | 470488.77 - 483650.82 |

| V 5 | 7595.511 | 3* | | 3p6.7h 2H* 9/2 - 3p6.8i 2I 11/2 | 470488.77 - 483650.82 |

| V 5 | 7595.511 | 3* | | 3p6.7h 2H* 11/2 - 3p6.8i 2I 13/2 | 470488.77 - 483650.82 |

+-------+----------+--------+---------+---------------------------------------------------------------+-----------------------+

+-------+-----------+-------+--------+----------------------------------+------+--------+------------------

| | | | new %1/| new conf1 + term1 / | new /| new %2/| new conf2+term2 /

| | | | | | rem. | |

+-------+-----------+-------+--------+----------------------------------+------+--------+------------------

| Co 18 | 6477900 | 1 | | 2s2.2p5.3s 3P* | or | | (2P*<3/2>) (3/2,1/2)*

| Co 18 | 6592400 | 1 | | 2s2.2p5.3s 1P* | or | | (2P*<1/2>) (1/2,1/2)*

| Co 18 | 8706000 | 1 | | 2s2.2p5.4s 3P* | or | | (2P*<3/2>) (3/2,1/2)*

| Co 18 | 8833000 | 1 | | 2s2.2p5.4s 1P* | or | | (2P*<1/2>) (1/2,1/2)*

| Cr 15 | 4714294 | 2 | | 2s2.2p5.(2P*<3/2>).3s (3/2,1/2)* | or | 100 | 2s2.2p5.3s 3P*

| | | | 100 | 2s2.2p5.3s 3P* | | |

| Cr 15 | 4727500 | 1 | | 2s2.2p5.(2P*<3/2>).3s (3/2,1/2)* | or | 50 | 2s2.2p5.3s 3P*

| | | | 50 | 2s2.2p5.3s 3P* | | 50 | 2s2.2p5.3s 1P*

| Cr 15 | 4793200 | 1 | | 2s2.2p5.(2P*<1/2>).3s (1/2,1/2)* | or | 50 | 2s2.2p5.3s 1P*

| | | | 50 | 2s2.2p5.3s 1P* | | 50 | 2s2.2p5.3s 3P*

| Cr 15 | 5259419 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[1/2]* | or | 94 | 2s2.2p5.3d 3P*

| | | | 94 | 2s2.2p5.3d 3P* | | |

| Cr 15 | 5324200 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[3/2]* | or | 83 | 2s2.2p5.3d 3D*

| | | | 83 | 2s2.2p5.3d 3D* | | 12 | 2s2.2p5.3d 1P*

| Cr 15 | 5406300 | 1 | | 2s2.2p5.(2P*<1/2>).3d 2[3/2]* | or | 86 | 2s2.2p5.3d 1P*

| | | | 86 | 2s2.2p5.3d 1P* | | |

| Cr 15 | 6577496 | 1 | | 2s2.2p5.(2P*<3/2>).4d 2[3/2]* | or | 53 | 2s2.2p5.4d 3D*

| | | | 53 | 2s2.2p5.4d 3D* | | 41 | 2s2.2p5.4d 1P*

| Cr 15 | 6641000 | 1 | | 2s2.2p5.(2P*<1/2>).4d 2[3/2]* | or | 59 | 2s2.2p5.4d 1P*

| | | | 59 | 2s2.2p5.4d 1P* | | 34 | 2s2.2p5.4d 3D*

| Cr 15 | 7148000 | 1 | | 2s2.2p5.5d 3D* | or | | (2P*<3/2>) 2[3/2]*

| Cr 15 | 7215000 | 1 | | 2s2.2p5.5d 1P* | or | | (2P*<1/2>) 2[3/2]*

| Cr 15 | 7452000 | 1 | | 2s2.2p5.6d 3D* | or | | (2P*<3/2>) 2[3/2]*

| Cr 15 | 7524000 | 1 | | 2s2.2p5.6d 1P* | or | | (2P*<1/2>) 2[3/2]*

| Fe 7 | 853307 | 4 | 30 | 3p6.3d.6f 1G* | | 33 | 3p6.3d.6f 3H*

| | | | 33 | 3p6.3d.6f 3H* | | 30 | 3p6.3d.6f 1G*

| Fe 7 | 855903 | 2 | 29 | 3p6.3d.6f 3D* | | 38 | 3p6.3d.6f 1D*

| | | | 38 | 3p6.3d.6f 1D* | | 29 | 3p6.3d.6f 3D*

| Fe 15 | 2386700 | 3 | 51 | 3p.4f 1F | | 46 | 3p.4f 3G

| | | | 57 | 3p.4f 3G | | 39 | 3p.4f 3F

| Kr 10 | 988265 | 5/2 | 26 | 3p6.3d8.(3P).4p 4P* | | 32 | 3p6.3d8.(3P).4p 2F*

| | | | 32 | 3p6.3d8.4p 2F* | | 26 | 3p6.3d8.(3P).4p 4P*

| Kr 28 | 15062000 | 3/2 | 36 | 2s2.2p4.(1S<0>).3d (0,3/2) | | 34 | 2s2.2p4.(1S<0>).3d (0,3/2

| Mn 16 | 5281200 | 1 | | 2s2.2p5.(2P*<3/2>).3s (3/2,1/2)* | or | 52 | 2s2.2p5.3s 3P*

| | | | 52 | 2s2.2p5.(2P*<3/2>).3s 3P* | | 48 | 2s2.2p5.(2P*<3/2>).3s 1P*

| Mn 16 | 5360800 | 1 | | 2s2.2p5.(2P*<1/2>).3s (1/2,1/2)* | or | 52 | 2s2.2p5.3s 1P*

| | | | 52 | 2s2.2p5.(2P*<1/2>).3s 1P* | | 48 | 2s2.2p5.(2P*<1/2>).3s 3P*

| Mn 16 | 5850249 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[1/2]* | or | 92 | 2s2.2p5.3d 3P*

| | | | 92 | 2s2.2p5.(2P*<3/2>).3d 3P* | | |

| Mn 16 | 5923500 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[3/2]* | or | 79 | 2s2.2p5.3d 3D*

| | | | 79 | 2s2.2p5.(2P*<3/2>).3d 3D* | | 14 | 2s2.2p5.(2P*<3/2>).3d 1P*

| Mn 16 | 6018300 | 1 | | 2s2.2p5.(2P*<1/2>).3d 2[3/2]* | or | 85 | 2s2.2p5.3d 1P*

| | | | 85 | 2s2.2p5.(2P*<1/2>).3d 1P* | | 13 | 2s2.2p5.(2P*<1/2>).3d 3D*

| Mn 16 | 7092000 | 1 | | 2s2.2p5.(2P*<3/2>).4s (3/2,1/2)* | or | 62 | 2s2.2p5.4s 3P*

| | | | 62 | 2s2.2p5.4s 3P* | | 37 | 2s2.2p5.4s 1P*

| Mn 16 | 7344868 | 1 | | 2s2.2p5.(2P*<3/2>).4d 2[3/2]* | or | 52 | 2s2.2p5.4d 3D*

| | | | 52 | 2s2.2p5.4d 3D* | | 44 | 2s2.2p5.4d 1P*

| Mn 16 | 7429000 | 1 | | 2s2.2p5.(2P*<1/2>).4d 2[3/2]* | or | 56 | 2s2.2p5.4d 1P*

| | | | 56 | 2s2.2p5.4d 1P* | | 35 | 2s2.2p5.4d 3D*

| Mn 16 | 7994000 | 1 | | 2s2.2p5.5d 3D* | or | | (2P*<3/2>) 2[3/2]*

| Mn 16 | 8084000 | 1 | | 2s2.2p5.5d 1P* | or | | (2P*<1/2>) 2[3/2]*

| Mn 16 | 8354000 | 1 | | 2s2.2p5.6d 3D* | or | | (2P*<3/2>) 2[3/2]*

| Mn 16 | 8439000 | 1 | | 2s2.2p5.6d 1P* | or | | (2P*<1/2>) 2[3/2]*

| Mo 6 | 315151 | 5/2 | 21 | 4p5.(2P*).4d2.(1G) 2F* | | 34 | 4p5.(2P*).4d2.(3F) 4F*

| | | | 34 | 4p5.(2P*).4d2 4F* | | 21 | 4p5.(2P*).4d2.(1G) 2F*

| Mo 6 | 316472 | 7/2 | 19 | 4p5.(2P*).4d2.(3F) 2F* | | 25 | 4p5.(2P*).4d2.(3P) 2F*

| | | | 25 | 4p5.(2P*).4d2 2F* | | 19 | 4p5.(2P*).4d2.(3F) 2F*

| Mo 6 | 462574 | 5/2 | 30 | 4p5.4d.(3D*).5s 4D* | | 45 | 4p5.4d.(1D*).5s 2D*

| | | | 45 | 4p5.(2P*).4d.(1D).5s 2D* | | 30 | 4p5.(2P*).4d.(3D).5s 4D*

| Mo 7 | 305558.9 | 1 | | 4s2.4p5.(2P*<3/2>).4d 2[1/2]* | or | | 4s2.4p5.4d 3P*

| | | | | 4p5.4d 3P* | | |

| Mo 7 | 341713.0 | 1 | | 4s2.4p5.(2P*<3/2>).4d 2[3/2]* | or | | 4s2.4p5.4d 3D*

| | | | | 4p5.4d 3D* | | |

| Mo 7 | 417528.6 | 1 | | 4s2.4p5.(2P*<1/2>).4d 2[3/2]* | or | | 4s2.4p5.4d 1P*

| | | | | 4p5.4d 1P* | | |

| Mo 7 | 481295.99 | 1 | | 4s2.4p5.(2P*<3/2>).5s 2[3/2]* | or | | (3/2,1/2)*

| | | | | 4p5.(2P*<3/2>).5s (3/2,1/2)* | | |

| Mo 7 | 502933.27 | 1 | | 4s2.4p5.(2P*<1/2>).5s 2[1/2]* | or | | (1/2,1/2)*

| | | | | 4p5.(2P*<1/2>).5s (1/2,1/2)* | | |

| Mo 7 | 659015.62 | 1 | | 4s2.4p5.(2P*<3/2>).5d 2[1/2]* | or | | 4s2.4p5.5d 3P*

| | | | | 4p5.5d 3P* | | |

| Mo 7 | 669063.09 | 1 | | 4s2.4p5.(2P*<3/2>).5d 2[3/2]* | or | | 4s2.4p5.5d 3D*

| | | | | 4p5.5d 3D* | | |

| Mo 7 | 689784.69 | 1 | | 4s2.4p5.(2P*<1/2>).5d 2[3/2]* | or | | 4s2.4p5.5d 1P*

| | | | | 4p5.5d 1P* | | |

| Mo 7 | 710068.9 | 1 | | 4s2.4p5.(2P*<3/2>).6s 2[3/2]* | or | | (3/2,1/2)*

| | | | | 4p5.(2P*<3/2>).6s (3/2,1/2)* | | |

| Mo 7 | 732582.5 | 1 | | 4s2.4p5.(2P*<1/2>).6s 2[1/2]* | or | | (1/2,1/2)*

| | | | | 4p5.(2P*<1/2>).6s (1/2,1/2)* | | |

| Mo 9 | 419123 | 2 | | 4s2.4p3.(2D*).4d 3P* | | |

| | | | 82 | 4s2.4p3.(2P*).4d 3P* | | 10 | 3s.3p5 3P*

| Mo 13 | 1126684 | 1 | | 3d10.4s.5p 3P* | or | | (1/2,1/2)*

| | | | | 4s.5p 3P* | | |

| Mo 13 | 1139342 | 1 | | 3d10.4s.5p 1P* | or | | (1/2,3/2)*

| | | | | 4s.5p 1P* | | |

| Mo 16 | 2171850 | 3/2 | 27 | 3p6.3d8.(3P).4p 2P* | | 22 | 3p6.3d8.(3P).4p 4D*

| | | | 15 | 3p6.3d8.4p 2D* | | 11 | 3p6.3d8.(1D).4p 2D*

| Mo 16 | 3019300 | 7/2 | 26 | 3p6.3d8.(1D<2>).4f 2[3]* | | 43 | 3p6.3d8.(1G<4>).4f 2[3]*

| | | | 43 | 3p6.3d8.(1G<4>).4f 2[3]* | | 26 | 3p6.3d8.(1D<2>).4f 2[3]*

| Mo 18 | 1242360 | 9/2 | 83 | 3p5.3d8.(3F) 4G* | | 16 | 3p5.3d8.(3F) 4F*

| | | | 86 | 3p5.3d8.(3F*) 4G* | | 12 | 3p5.3d8.(3F*) 4F*

| Mo 18 | 1280420 | 7/2 | 29 | 3p5.3d8.(3F) 4G* | | 29 | 3p5.3d8.(3F) 4F*

| | | | 36 | 3p5.3d8 (3P*)4D* | | 31 | 3p5.3d8.(3F*) 4G*

| Mo 18 | 1284110 | 9/2 | 46 | 3p5.3d8.(3F) 4F* | | 25 | 3p5.3d8.(1G) 2G*

| | | | 46 | 3p5.3d8.(3F*) 4F* | | 26 | 3p5.3d8.(1G*) 2G*

| Mo 18 | 1306770 | 7/2 | 64 | 3p5.3d8.(3P) 4D* | | 12 | 3p5.3d8.(3F) 4F*

| | | | 54 | 3p5.3d8.(3P*) 4D* | | 13 | 3p5.3d8.(3F*) 4G*

| Mo 18 | 1307600 | 5/2 | 38 | 3p5.3d8.(3P) 4P* | | 25 | 3p5.3d8.(3P) 4D*

| | | | 47 | 3p5.3d8.(3P*) 4P* | | 30 | 3p5.3d8.(3P*) 4D*

| Mo 18 | 1320790 | 7/2 | 30 | 3p5.3d8.(1G) 2G* | | 20 | 3p5.3d8.(3F) 4F*

| | | | 30 | 3p5.3d8 (3F*)4F* | | 27 | 3p5.3d8.(1G*) 2G*

| Mo 18 | 1322740 | 5/2 | 37 | 3p5.3d8.(3F) 4F* | | 31 | 3p5.3d8.(3P) 4P*

| | | | 45 | 3p5.3d8.(3F*) 4F* | | 22 | 3p5.3d8.(3P*) 4P*

| Mo 18 | 1336120 | 3/2 | 36 | 3p5.3d8.(3P) 4P* | | 21 | 3p5.3d8.(3F) 4F*

| | | | 40 | 3p5.3d8.(3P*) 4P* | | 17 | 3p5.3d8.(3P*) 4D*

| Mo 18 | 1354790 | 9/2 | 41 | 3p5.3d8.(1G) 2G* | | 32 | 3p5.3d8.(3F) 4F*

| | | | 38 | 3p5.3d8 (1G*)2G* | | 35 | 3p5.3d8.(3F*) 4F*

| Mo 18 | 1362690 | 7/2 | 27 | 3p5.3d8.(1G) 2G* | | 23 | 3p5.3d8.(1D) 2F*

| | | | 26 | 3p5.3d8 (1G*)2G* | | 22 | 3p5.3d8.(1D*) 2F*

| Mo 18 | 1377840 | 5/2 | 33 | 3p5.3d8.(3P) 4D* | | 30 | 3p5.3d8.(3F) 4D*

| | | | 31 | 3p5.3d8 (3P*)4D* | | 22 | 3p5.3d8.(3F*) 4G*

| Mo 18 | 1383380 | 5/2 | 35 | 3p5.3d8.(3F) 4G* | | 20 | 3p5.3d8.(1D) 2D*

| | | | 27 | 3p5.3d8 (3F*)4D* | | 20 | 3p5.3d8.(3F*) 2D*

| Mo 18 | 1406680 | 7/2 | 37 | 3p5.3d8.(3F) 4D* | | 28 | 3p5.3d8.(3F) 4F*

| | | | 35 | 3p5.3d8 (3F*)4D* | | 26 | 3p5.3d8.(3F*) 4F*

| Mo 18 | 1479650 | 5/2 | 22 | 3p5.3d8.(1D) 2D* | | 19 | 3p5.3d8.(1G) 2F*

| | | | 23 | 3p5.3d8 (1G*)2F* | | 21 | 3p5.3d8.(1D*) 2D*

| Mo 18 | 1492600 | 7/2 | 42 | 3p5.3d8.(3F) 2F* | | 19 | 3p5.3d8.(3F) 4D*

| | | | 40 | 3p5.3d8 (3F*)2F* | | 24 | 3p5.3d8.(3F*) 4D*

| Mo 18 | 1494810 | 9/2 | 74 | 3p5.3d8.(1G) 2H* | | 13 | 3p5.3d8.(3F) 2G*

| | | | 71 | 3p5.3d8.(1G*) 2H* | | 15 | 3p5.3d8.(3F*) 2G*

| Mo 18 | 1517570 | 7/2 | 49 | 3p5.3d8.(3F) 2G* | | 40 | 3p5.3d8.(1G) 2F*

| | | | 52 | 3p5.3d8.(3F*) 2G* | | 34 | 3p5.3d8.(1G*) 2F*

| Mo 18 | 1559730 | 5/2 | 43 | 3p5.3d8.(1D) 2F* | | 31 | 3p5.3d8.(3F) 2F*

| | | | 39 | 3p5.3d8.(1D*) 2F* | | 32 | 3p5.3d8.(3F*) 2F*

| Mo 18 | 1574310 | 9/2 | 66 | 3p5.3d8.(3F) 2G* | | 24 | 3p5.3d8.(1G) 2G*

| | | | 63 | 3p5.3d8.(3F*) 2G* | | 27 | 3p5.3d8.(1G*) 2G*

| Mo 18 | 1610200 | 7/2 | 34 | 3p5.3d8.(1G) 2F* | | 26 | 3p5.3d8.(3F) 2G*

| | | | 41 | 3p5.3d8.(1G*) 2F* | | 24 | 3p5.3d8.(1G*) 2G*

| Mo 18 | 1615600 | 5/2 | 60 | 3p5.3d8.(3P) 2D* | | 22 | 3p5.3d8.(3F) 2D*

| | | | 58 | 3p5.3d8.(3P*) 2D* | | 23 | 3p5.3d8.(3F*) 2D*

| Mo 18 | 1646000 | 3/2 | 60 | 3p5.3d8.(3P) 2P* | | 14 | 3p5.3d8.(3P) 2D*

| | | | 61 | 3p5.3d8.(3P*) 2P* | | 12 | 3p5.3d8.(3P*) 2D*

| Ni 19 | 7807700 | 1 | 77 | 2s2.2p5.(2P*<3/2>).3d (3/2,3/2)* | or | 91 | 2s2.2p5.3d 3P*

| | | | 91 | 2s2.2p5.3d 3P* | | 9 | 2s2.2p5.3d 3D*

| Ni 19 | 7901400 | 1 | 64 | 2s2.2p5.(2P*<3/2>).3d (3/2,5/2)* | or | 67 | 2s2.2p5.3d 3D*

| | | | 67 | 2s2.2p5.3d 3D* | | 28 | 2s2.2p5.3d 1P*

| Ni 19 | 8041800 | 1 | 85 | 2s2.2p5.(2P*<1/2>).3d (1/2,3/2)* | or | 72 | 2s2.2p5.3d 1P*

| | | | 72 | 2s2.2p5.3d 1P* | | 24 | 2s2.2p5.3d 3D*

| P 3 | 188215.25 | 5/2 | 97 | 3s.3p.(3P*).3d 2F* | | | 3p2.(1S).4f 2F*

| | | | 97 | 3s.3p.(3P*).3d 2F* | | 0 | 3p2.(1S).4f 2F*

| P 3 | 188677.37 | 7/2 | 97 | 3s.3p.(3P*).3d 2F* | | | 3p2.(1S).4f 2F*

| | | | 97 | 3s.3p.(3P*).3d 2F* | | 0 | 3p2.(1S).4f 2F*

| Ti 13 | 3709200 | 1 | | 2s2.2p5.(2P*<3/2>).3s (3/2,1/2)* | or | 55 | 2s2.2p5.3s 3P*

| | | | 55 | 2s2.2p5.3s 3P* | | 45 | 2s2.2p5.3s 1P*

| Ti 13 | 3753600 | 1 | | 2s2.2p5.(2P*<1/2>).3s (1/2,1/2)* | or | 55 | 2s2.2p5.3s 1P*

| | | | 55 | 2s2.2p5.3s 1P* | | 45 | 2s2.2p5.3s 3P*

| Ti 13 | 4168326 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[1/2]* | or | 94 | 2s2.2p5.3d 3P*

| | | | 94 | 2s2.2p5.3d 3P* | | |

| Ti 13 | 4219800 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[3/2]* | or | 86 | 2s2.2p5.3d 3D*

| | | | 86 | 2s2.2p5.3d 3D* | | |

| Ti 13 | 4281600 | 1 | | 2s2.2p5.(2P*<1/2>).3d 2[3/2]* | or | 90 | 2s2.2p5.3d 1P*

| | | | 90 | 2s2.2p5.3d 1P* | | |

| Ti 13 | 4966500 | 1 | | 2s2.2p5.(2P*<3/2>).4s (3/2,1/2)* | or | 59 | 2s2.2p5.4s 3P*

| | | | 59 | 2s2.2p5.4s 3P* | | 41 | 2s2.2p5.4s 1P*

| Ti 13 | 5014300 | 1 | | 2s2.2p5.(2P*<1/2>).4s (1/2,1/2)* | or | 59 | 2s2.2p5.4s 1P*

| | | | 59 | 2s2.2p5.4s 1P* | | 41 | 2s2.2p5.4s 3P*

| Ti 13 | 5163700 | 1 | | 2s2.2p5.(2P*<3/2>).4d 2[3/2]* | or | 61 | 2s2.2p5.4d 3D*

| | | | 61 | 2s2.2p5.4d 3D* | | 34 | 2s2.2p5.4d 1P*

| Ti 13 | 5207200 | 1 | | 2s2.2p5.(2P*<1/2>).4d 2[3/2]* | or | 66 | 2s2.2p5.4d 1P*

| | | | 66 | 2s2.2p5.4d 1P* | | 28 | 2s2.2p5.4d 3D*

| Ti 13 | 5596300 | 1 | | 2s2.2p5.(2P*<3/2>).5d 2[3/2]* | or | | 2s2.2p5.5d 3D*

| Ti 13 | 5641100 | 1 | | 2s2.2p5.(2P*<1/2>).5d 2[3/2]* | or | | 2s2.2p5.5d 1P*

| V 14 | 4202700 | 1 | | 2s2.2p5.(2P*<3/2>).3s (3/2,1/2)* | or | | 3P*

| V 14 | 4257100 | 1 | | 2s2.2p5.(2P*<1/2>).3s (1/2,1/2)* | or | | 1P*

| V 14 | 4696000 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[1/2]* | or | | 3P*

| V 14 | 4757800 | 1 | | 2s2.2p5.(2P*<3/2>).3d 2[3/2]* | or | | 3D*

| V 14 | 4827200 | 1 | | 2s2.2p5.(2P*<1/2>).3d 2[3/2]* | or | | 1P*

| V 14 | 5632000 | 1 | | 2s2.2p5.4s 3P* | or | | (2P*<3/2>) (3/2,1/2)*

| V 14 | 5690000 | 1 | | 2s2.2p5.4s 1P* | or | | (2P*<1/2>) (1/2,1/2)*

| V 14 | 5850000 | 1 | | 2s2.2p5.(2P*<3/2>).4d 2[3/2]* | or | | 2s2.2p5.4d 3D*

| V 14 | 5904000 | 1 | | 2s2.2p5.(2P*<1/2>).4d 2[3/2]* | or | | 2s2.2p5.4d 1P*

| V 14 | 6350000 | 1 | | 2s2.2p5.(2P*<3/2>).5d 2[3/2]* | or | | 2s2.2p5.5d 3D*

| V 14 | 6407000 | 1 | | 2s2.2p5.(2P*<1/2>).5d 2[3/2]* | or | | 2s2.2p5.5d 1P*

+-------+-----------+-------+--------+----------------------------------+------+--------+--------------------------

2.2. Line changes in ASD

2.2.1. Line identification changes in ASD

Line identification was assigned to 171 previously unclassified lines in ASD based on the line list of Monograph 8. The lines were identified based on close match or coincidence of the observed wavelengths. The list of these lines is given below.

+------+----------+---------+---------+---------+----------------------------------------------------------------+-----------+---------+

+------+----------+---------+---------+---------+----------------------------------------------------------------+-----------+---------+

| Cr 5 | 438.618 | 438.62 | 10 | 100 | 3p6.3d2 3F 4 - 3p6.3d.4p 3D* 3 | 1w | 379 |

| Cr 5 | 825.600 | 825.60 | 7 | 50 | 3p6.3d.4p 1F* 3 - 3p6.3d.5s 1D 2 | 1w | 380 |

| Cr 5 | 968.703 | 968.70 | 7 | 50 | 3p6.3d.4p 1D* 2 - 3p6.3d.4d 1D 2 | 1w | 380 |

| Cr 5 | 1045.044 | 1045.04 | 7 | 50 | 3p6.3d.4p 3P* 2 - 3p6.3d.4d 3P 2 | 1w | 380 |

| Cr 5 | 1060.651 | 1060.65 | 8 | 60 | 3p6.3d.4p 1F* 3 - 3p6.3d.4d 1G 4 | 1w | 380 |

| Cr 5 | 1112.452 | 1112.45 | 7 | 50 | 3p6.3d.4p 3D* 1 - 3p6.3d.4d 3D 1 | 1w | 380 |

| Cr 5 | 1114.350 | 1114.35 | 8 | 60 | 3p6.3d.4p 3D* 2 - 3p6.3d.4d 3D 2 | 1w | 380 |

| Cr 5 | 1116.478 | 1116.48 | 10 | 100 | 3p6.3d.4p 3F* 2 - 3p6.3d.4d 3G 3 | 1w | 380 |

| Cr 5 | 1117.559 | 1117.56 | 9 | 80 | 3p6.3d.4p 3D* 3 - 3p6.3d.4d 3D 3 | 1w | 380 |

| Cr 5 | 1118.157 | 1118.16 | 7 | 50 | 3p6.3d.4p 1P* 1 - 3p6.3d.4d 1D 2 | 1w | 380 |

| Cr 5 | 1193.950 | 1193.95 | 10 | 100 | 3p6.3d.4p 3P* 2 - 3p6.3d.4d 3D 3 | 1w | 380 |

| Cr 5 | 1196.042 | 1196.04 | 9 | 80 | 3p6.3d.4p 3P* 1 - 3p6.3d.4d 3D 2 | 1w | 380 |

| Cr 5 | 1210.499 | 1210.50 | 7 | 50 | 3p6.3d.4p 1P* 1 - 3p6.3d.4d 3S 1 | 1w | 380 |

| Cr 5 | 1259.986 | 1259.99 | 7 | 50 | 3p6.3d.4p 1P* 1 - 3p6.3d.4d 1P 1 | 1w | 380 |

| Cr 5 | 1263.501 | 1263.50 | 10 | 100 | 3p6.3d.4p 1F* 3 - 3p6.3d.4d 1F 3 | 1w | 380 |

| Kr 5 | 472.19 | 472.16 | 7 | 150 | 4s2.4p2 3P 2 - 4s2.4p.4d 3D* 3 | 2w | 421 |

| Kr 5 | 500.84 | 500.77 | 2 | 120 | 4s2.4p2 1D 2 - 4s2.4p.4d 3D* 3 | 2w | 421 |

| Kr 5 | 507.23 | 507.20 | 2 | 200 | 4s2.4p2 1D 2 - 4s2.4p.4d 1D* 2 | 2w | 421 |

| Kr 5 | 691.84 | 691.75 | 10 | -1 | 4s2.4p2 3P 1 - 4s.4p3 3P* 1 | 2w | 409 |

| Kr 5 | 708.85 | 708.85 | 10 | 600 | 4s2.4p2 3P 2 - 4s.4p3 3P* 2 | 2w | 421 |

| Ti 3 | 1282.484 | 1282.48 | 6 | 6 | 3p6.3d2 3F 3 - 3p6.3d.4p 3F* 4 | 1w | 378 |

| Ti 3 | 1286.228 | 1286.36 | 6 | 15 | 3p6.3d2 3F 2 - 3p6.3d.4p 3F* 3 | 1w | 378 |

| Ti 3 | 1294.698 | 1294.70 | 15 | 15 | 3p6.3d2 3F 3 - 3p6.3d.4p 3F* 2 | 1w | 378 |

| Ti 3 | 1295.883 | 1295.88 | 10 | 10 | 3p6.3d2 3F 2 - 3p6.3d.4p 3D* 2 | 1w | 378 |

| Ti 3 | 1298.659 | 1298.66 | 20 | 20 | 3p6.3d2 3F 2 - 3p6.3d.4p 3D* 1 | 1w | 378 |

| Ti 3 | 1421.767 | 1421.77 | 10 | 10 | 3p6.3d2 3P 1 - 3p6.3d.4p 3P* 1 | 1w | 378 |

| Ti 3 | 2327.019 | 2327.02 | 10 | 10 | 3p6.3d.4s 3D 1 - 3p6.3d.4p 3P* 2 | 1w | 378 |

| Ti 3 | 2527.840 | 2527.84 | 24 | 24 | 3p6.3d.4s 3D 2 - 3p6.3d.4p 3F* 3 | 1w | 378 |

| Ti 3 | 2540.057 | 2540.06 | 23 | 23 | 3p6.3d.4s 3D 1 - 3p6.3d.4p 3F* 2 | 1w | 378 |

| Ti 3 | 2563.436 | 2563.44 | 24 | 24 | 3p6.3d.4s 3D 3 - 3p6.3d.4p 3D* 3 | 1w | 378 |

| Ti 3 | 2565.423 | 2565.42 | 23 | 23 | 3p6.3d.4s 3D 2 - 3p6.3d.4p 3D* 2 | 1w | 378 |

| Ti 3 | 2580.456 | 2580.46 | 15 | 15 | 3p6.3d.4s 3D 3 - 3p6.3d.4p 3D* 2 | 1w | 378 |

| Ti 3 | 2692.158 | 2692.16 | 10 | 10 | 3p6.3d.4s 3D 1 - 3p6.3d.4p 1D* 2 | 1w | 378 |

| Ti 3 | 2701.956 | 2701.96 | 12 | 12 | 3p6.3d.4s 3D 2 - 3p6.3d.4p 1D* 2 | 1w | 378 |

| Ti 3 | 3893.629 | 3893.63 | 12 | 12 | 3p6.3d.4d 3F 2 - 3p6.3d.4f 3G* 3 | 1w | 378 |

| Ti 3 | 3896.330 | 3896.33 | 10 | 10 | 3p6.3d.4d 3F 3 - 3p6.3d.4f 3G* 4 | 1w | 378 |

| Ti 3 | 3921.384 | 3921.38 | 12 | 12 | 3p6.3d.4d 3F 4 - 3p6.3d.4f 3G* 4 | 1w | 378 |

| Ti 3 | 3921.611 | 3921.61 | 10 | 10 | 3p6.3d.4d 3F 2 - 3p6.3d.4f 3F* 3 | 1w | 378 |

| Ti 3 | 3922.953 | 3922.95 | 12 | 12 | 3p6.3d.4d 3F 3 - 3p6.3d.4f 3F* 4 | 1w | 378 |

| Ti 3 | 4060.208 | 4060.21 | 10 | 10 | 3p6.3d.5s 1D 2 - 3p6.3d.4f 1F* 3 | 1w | 378 |

| Ti 3 | 4348.04 | 4348.04 | 10 | 10 | 3p6.3d.4f 3D* 3 - 3p6.3d.(2D<5/2>).5g 2[7/2] 4 | 1w | 378 |

| Ti 3 | 4540.216 | 4540.22 | 10 | 10 | 3p6.3d.5p 3D* 2 - 3p6.3d.5d 3F 3 | 1w | 378 |

| Ti 3 | 4549.842 | 4549.84 | 15 | 15 | 3p6.3d.5p 3D* 3 - 3p6.3d.5d 3F 4 | 1w | 378 |

| Ti 3 | 4572.204 | 4572.20 | 15bl | 15bl | 3p6.3d.5p 3D* 2 - 3p6.3d.5d 3F 2 | 1w | 378 |

| Ti 3 | 4950.104 | 4950.10 | 10 | 10 | 3p6.3d.5p 3F* 3 - 3p6.3d.5d 3G 4 | 1w | 378 |

| Ti 3 | 5278.70 | 5278.70 | 10 | 10 | 3p6.3d.5p 3P* 2 - 3p6.3d.5d 3D 3 | 1w | 378 |

| Ti 3 | 5298.43 | 5298.43 | 12 | 12 | 3p6.3d.4p 1P* 1 - 3p6.4s2 1S 0 | 1w | 378 |

| Ti 3 | 5301.20 | 5301.20 | 16 | 16 | 3p6.3d.4d 3G 4 - 3p6.3d.5p 3F* 3 | 1w | 378 |

| Ti 3 | 5306.88 | 5306.88 | 15 | 15 | 3p6.3d.4d 3G 3 - 3p6.3d.5p 3F* 2 | 1w | 378 |

| Ti 3 | 5817.44 | 5817.44 | 10 | 10 | 3p6.3d.4d 1S 0 - 3p6.4s.4p 1P* 1 | 1w | 378 |

| Ti 3 | 6621.58 | 6621.58 | 18 | 18 | 3p6.3d.5s 1D 2 - 3p6.3d.5p 1F* 3 | 1w | 378 |

| Ti 3 | 6707.76 | 6707.76 | 14 | 14 | 3p6.3d.4d 3F 3 - 3p6.3d.5p 3F* 3 | 1w | 378 |

| Ti 3 | 6724.80 | 6724.80 | 12 | 12 | 3p6.3d.4d 3F 2 - 3p6.3d.5p 3F* 2 | 1w | 378 |

| Ti 3 | 6734.10 | 6734.10 | 16 | 16 | 3p6.3d.5s 1D 2 - 3p6.3d.5p 1P* 1 | 1w | 378 |

| Ti 3 | 6862.26 | 6862.26 | 15 | 15 | 3p6.3d.4d 3F 4 - 3p6.3d.5p 3D* 3 | 1w | 378 |

| Ti 3 | 6874.35 | 6874.35 | 12 | 12 | 3p6.3d.4d 3F 3 - 3p6.3d.5p 3D* 2 | 1w | 378 |

| Ti 3 | 7084.57 | 7084.57 | 18 | 18 | 3p6.3d.5s 3D 2 - 3p6.3d.5p 3F* 3 | 1w | 378 |

| Ti 3 | 7124.13 | 7124.13 | 15 | 15 | 3p6.3d.5s 3D 1 - 3p6.3d.5p 3F* 2 | 1w | 378 |

| Ti 3 | 7171.79 | 7171.79 | 11 | 11 | 3p6.3d.5s 3D 2 - 3p6.3d.5p 3D* 3 | 1w | 378 |

| Ti 3 | 7175.92 | 7175.92 | 10 | 10 | 3p6.3d.5s 3D 2 - 3p6.3d.5p 3F* 2 | 1w | 378 |

| Ti 3 | 7217.50 | 7217.50 | 10 | 10 | 3p6.3d.5s 3D 1 - 3p6.3d.5p 3D* 2 | 1w | 378 |

| Ti 3 | 7225.55 | 7225.55 | 9 | 9 | 3p6.3d.5s 3D 3 - 3p6.3d.5p 3F* 3 | 1w | 378 |

| Ti 3 | 7270.67 | 7270.67 | 12 | 12 | 3p6.3d.5s 3D 2 - 3p6.3d.5p 3D* 2 | 1w | 378 |

| Ti 3 | 7316.30 | 7316.30 | 14 | 14 | 3p6.3d.5s 3D 3 - 3p6.3d.5p 3D* 3 | 1w | 378 |

| Ti 3 | 7457.85 | 7457.85 | 10 | 10 | 3p6.3d.5d 3D 3 - 3p6.3d.5f 3F* 4 | 1w | 378 |

| Ti 3 | 7523.85 | 7523.85 | 10 | 10 | 3p6.3d.5d 3G 3 - 3p6.3d.5f 3H* 4 | 1w | 378 |

| Ti 3 | 8172.21 | 8172.21 | 10 | 10w | 3p6.3d.(2D<3/2>).5g 2[9/2] 5 - 3p6.3d.(2D<3/2>).6h 2[11/2]* 6 | 1w | 378 |

| Ti 3 | 8173.37 | 8173.37 | 9 | 9w | 3p6.3d.(2D<3/2>).5g 2[9/2] 4 - 3p6.3d.(2D<3/2>).6h 2[11/2]* 5 | 1w | 378 |

| Ti 3 | 8178.00 | 8178.00 | 9 | 9w | 3p6.3d.(2D<5/2>).5g 2[9/2] 5 - 3p6.3d.(2D<5/2>).6h 2[11/2]* 6 | 1w | 378 |

| Ti 3 | 8182.42 | 8182.42 | 10 | 10 | 3p6.3d.4d 3P 2 - 3p6.3d.5p 3D* 3 | 1w | 378 |

| Ti 3 | 8192.68 | 8192.68 | 9 | 9w | 3p6.3d.(2D<5/2>).5g 2[11/2] 5 - 3p6.3d.(2D<5/2>).6h 2[13/2]* 6 | 1w | 378 |

| Ti 3 | 8194.75 | 8194.75 | 9 | 9w | 3p6.3d.(2D<5/2>).5g 2[11/2] 6 - 3p6.3d.(2D<5/2>).6h 2[13/2]* 7 | 1w | 378 |

| Ti 3 | 8263.67 | 8263.67 | 9 | 9w | 3p6.3d.(2D<5/2>).5g 2[13/2] 7 - 3p6.3d.(2D<5/2>).6h 2[15/2]* 8 | 1w | 378 |

| Ti 3 | 8267.32 | 8267.32 | 15 | 15w | 3p6.3d.(2D<3/2>).5g 2[5/2] 2 - 3p6.3d.(2D<3/2>).6h 2[7/2]* 3 | 1w | 378 |

| Ti 3 | 8466.87 | 8466.87 | 20 | 20 | 3p6.3d.4d 1D 2 - 3p6.3d.5p 1D* 2 | 1w | 378 |

| Ti 3 | 8699.85 | 8699.85 | 5 | 5 | 3p6.3d.4d 3P 2 - 3p6.3d.5p 1D* 2 | 1w | 378 |

| Ti 4 | 2359.142 | 2359.14 | 10 | 10 | 3p6.4f 2F* 5/2 - 3p6.5g 2G 7/2 | 3w | 428 |

| Ti 4 | 2359.499 | 2359.50 | 10 | 10 | 3p6.4f 2F* 7/2 - 3p6.5g 2G 9/2 | 3w | 428 |

| Ti 4 | 4131.215 | 4131.22 | 13 | 13 | 3p6.5f 2F* 5/2 - 3p6.6g 2G 7/2 | 3w | 428 |

| Ti 4 | 4133.779 | 4133.78 | 14 | 14 | 3p6.5f 2F* 7/2 - 3p6.6g 2G 9/2 | 3w | 428 |

| Ti 4 | 4618.114 | 4618.11 | 15* | 15 | 3p6.5g 2G 9/2 - 3p6.6h 2H* 9/2 | 3w | 428 |

| Ti 4 | 5470.98 | 5470.98 | 8 | 8 | 3p6.6p 2P* 1/2 - 3p6.7s 2S 1/2 | 3w | 428 |

| Ti 4 | 5517.72 | 5517.72 | 10 | 10 | 3p6.6p 2P* 3/2 - 3p6.7s 2S 1/2 | 3w | 428 |

| Ti 4 | 5877.79 | 5877.79 | 14 | 14 | 3p6.5d 2D 3/2 - 3p6.5f 2F* 5/2 | 3w | 428 |

| Ti 4 | 5885.96 | 5885.96 | 15 | 15 | 3p6.5d 2D 5/2 - 3p6.5f 2F* 7/2 | 3w | 428 |

| Ti 4 | 5891.15 | 5891.15 | 7 | 7 | 3p6.5d 2D 5/2 - 3p6.5f 2F* 5/2 | 3w | 428 |

| Ti 4 | 6231.62 | 6231.62 | 6 | 6 | 3p6.5d 2D 3/2 - 3p6.6p 2P* 3/2 | 3w | 428 |

| Ti 4 | 6246.65 | 6246.65 | 17 | 17 | 3p6.5d 2D 5/2 - 3p6.6p 2P* 3/2 | 3w | 428 |

| Ti 4 | 6247.74 | 6247.74 | 11 | 11 | 3p6.5d 2D 3/2 - 3p5.3d2 2F* 5/2 | 3w | 428 |

| Ti 4 | 6292.41 | 6292.41 | 15 | 15 | 3p6.5d 2D 3/2 - 3p6.6p 2P* 1/2 | 3w | 428 |

| Ti 4 | 6913.85 | 6913.85 | 12 | 12 | 3p6.6p 2P* 1/2 - 3p6.6d 2D 3/2 | 3w | 428 |

| Ti 4 | 6978.51 | 6978.51 | 15 | 15 | 3p6.6p 2P* 3/2 - 3p6.6d 2D 5/2 | 3w | 428 |

| Ti 4 | 7491.37 | 7491.37 | 9 | 9 | 3p6.5f 2F* 7/2 - 3p6.6d 2D 5/2 | 3w | 428 |

| Ti 4 | 7494.77 | 7494.77 | 8 | 8 | 3p6.5f 2F* 5/2 - 3p6.6d 2D 3/2 | 3w | 428 |

| Ti 4 | 7652.12 | 7652.12 | 5* | 5w | 3p6.6g 2G 9/2 - 3p6.7h 2H* 9/2 | 3w | 428 |

| Ti 4 | 7706.85 | 7706.85 | 8 | 8w | 3p6.6h 2H* 9/2 - 3p6.7i 2I 11/2 | 3w | 428 |

| Ti 5 | 461.414 | 461.41 | 7 | 7 | 3s2.3p5.3d 3P* 2 - 3s2.3p5.4p 1D 2 | 4w | 427 |

| Ti 5 | 474.690 | 474.69 | 8 | 8 | 3s2.3p5.3d 3P* 2 - 3s2.3p5.4p 3D 3 | 4w | 427 |

| Ti 5 | 483.992 | 483.99 | 8 | 8 | 3s2.3p5.3d 3P* 1 - 3s2.3p5.4p 3S 1 | 4w | 427 |

| Ti 5 | 488.582 | 488.58 | 10 | 10bl | 3s2.3p5.3d 3P* 2 - 3s2.3p5.4p 3S 1 | 4w | 427 |

| Ti 5 | 498.260 | 498.26 | 15 | 15 | 3s2.3p5.3d 3F* 4 - 3s2.3p5.4p 3D 3 | 4w | 427 |

| Ti 5 | 502.077 | 502.08 | 14 | 14 | 3s2.3p5.3d 3F* 3 - 3s2.3p5.4p 3D 2 | 4w | 427 |

| Ti 5 | 502.711 | 502.71 | 7 | 7 | 3s2.3p5.3d 3F* 3 - 3s2.3p5.4p 3D 3 | 4w | 427 |

| Ti 5 | 504.665 | 504.66 | 12 | 12 | 3s2.3p5.3d 3F* 2 - 3s.3p6.3d 3D 1 | 4w | 427 |

| Ti 5 | 506.468 | 506.47 | 7 | 7 | 3s2.3p5.3d 3F* 2 - 3s2.3p5.4p 3D 2 | 4w | 427 |

| Ti 5 | 513.374 | 513.37 | 8 | 8 | 3s2.3p5.3d 1F* 3 - 3s.3p6.3d 1D 2 | 4w | 427 |

| Ti 5 | 523.050 | 523.05 | 7 | 7 | 3s2.3p5.3d 1D* 2 - 3s2.3p5.4p 3P 2 | 4w | 427 |

| Ti 5 | 524.578 | 524.58 | 12 | 12 | 3s2.3p5.3d 3D* 3 - 3s2.3p5.4p 3P 2 | 4w | 427 |

| Ti 5 | 526.570 | 526.57 | 13 | 13 | 3s2.3p5.3d 3D* 2 - 3s2.3p5.4p 3P 1 | 4w | 427 |

| Ti 5 | 529.315 | 529.32 | 8 | 8 | 3s2.3p5.3d 3D* 1 - 3s2.3p5.4p 3P 0 | 4w | 427 |

| Ti 5 | 535.836 | 535.84 | 10 | 10 | 3s2.3p5.3d 1F* 3 - 3s2.3p5.4p 3P 2 | 4w | 427 |

| Ti 5 | 535.888 | 535.89 | 10 | 10 | 3s2.3p5.3d 3D* 3 - 3s2.3p5.4p 1D 2 | 4w | 427 |

| Ti 5 | 540.145 | 540.14 | 8 | 8bl | 3s2.3p5.3d 3D* 3 - 3s.3p6.3d 3D 3 | 4w | 427 |

| Ti 5 | 541.459 | 541.46 | 8 | 8 | 3s2.3p5.3d 1D* 2 - 3s.3p6.3d 3D 2 | 4w | 427 |

| Ti 5 | 541.711 | 541.71 | 9 | 9 | 3s2.3p5.3d 3D* 2 - 3s2.3p5.4p 1D 2 | 4w | 427 |

| Ti 5 | 543.103 | 543.10 | 7 | 7 | 3s2.3p5.3d 3D* 3 - 3s.3p6.3d 3D 2 | 4w | 427 |

| Ti 5 | 543.339 | 543.34 | 7 | 7 | 3s2.3p5.3d 3D* 1 - 3s2.3p5.4p 3D 1 | 4w | 427 |

| Ti 5 | 1128.546 | 1128.55 | 7 | 7 | 3s2.3p5.4p 3S 1 - 3s2.3p5.(2P*<3/2>).4d 2[3/2]* 2 | 4w | 427 |

| Ti 5 | 1192.353 | 1192.35 | 8 | 8 | 3s2.3p5.4p 3D 2 - 3s2.3p5.(2P*<3/2>).4d 2[7/2]* 3 | 4w | 427 |

| Ti 5 | 1198.659 | 1198.66 | 9 | 9 | 3s2.3p5.4p 3D 3 - 3s2.3p5.(2P*<3/2>).4d 2[7/2]* 4 | 4w | 427 |

| Ti 5 | 1222.359 | 1222.36 | 9 | 9 | 3s2.3p5.4p 1P 1 - 3s2.3p5.(2P*<1/2>).4d 2[5/2]* 2 | 4w | 427 |

| Ti 5 | 1230.361 | 1230.36 | 10 | 10 | 3s2.3p5.4p 3P 2 - 3s2.3p5.(2P*<1/2>).4d 2[5/2]* 3 | 4w | 427 |

| Ti 5 | 1239.958 | 1239.96 | 11 | 11 | 3s2.3p5.4p 3P 2 - 3s2.3p5.(2P*<1/2>).4d 2[5/2]* 2 | 4w | 427 |

| Ti 5 | 1241.671 | 1241.67 | 10 | 10 | 3s2.3p5.4p 3D 1 - 3s2.3p5.(2P*<3/2>).4d 2[5/2]* 2 | 4w | 427 |

| Ti 5 | 1246.131 | 1246.13 | 7 | 7 | 3s2.3p5.4p 3P 1 - 3s2.3p5.(2P*<1/2>).4d 2[3/2]* 2 | 4w | 427 |

| Ti 5 | 1268.490 | 1268.49 | 8 | 8 | 3s.3p6.3d 3D 3 - 3s2.3p5.(2P*<3/2>).4d 2[7/2]* 4 | 4w | 427 |

| Ti 5 | 1306.108 | 1306.11 | 8 | 8 | 3s2.3p5.4p 1D 2 - 3s2.3p5.(2P*<3/2>).4d 2[3/2]* 2 | 4w | 427 |

| Ti 5 | 1411.309 | 1411.31 | 8 | 8 | 3s2.3p5.4s 1P* 1 - 3s2.3p5.4p 1S 0 | 4w | 427 |

| Ti 5 | 1675.150 | 1675.15 | 9 | 9 | 3s2.3p5.4s 3P* 2 - 3s2.3p5.4p 1D 2 | 4w | 427 |

| Ti 5 | 1687.165 | 1687.16 | 8 | 8 | 3s2.3p5.4s 3P* 0 - 3s2.3p5.4p 3P 1 | 4w | 427 |

| Ti 5 | 1717.396 | 1717.40 | 11 | 11 | 3s2.3p5.4s 3P* 2 - 3s.3p6.3d 3D 3 | 4w | 427 |

| Ti 5 | 1759.757 | 1759.76 | 8 | 8 | 3s2.3p5.4s 3P* 0 - 3s2.3p5.4p 1P 1 | 4w | 427 |

| Ti 5 | 1771.452 | 1771.45 | 7 | 7 | 3s2.3p5.4s 3P* 1 - 3s2.3p5.4p 3D 1 | 4w | 427 |

| Ti 5 | 1841.490 | 1841.49 | 10 | 10 | 3s2.3p5.4s 1P* 1 - 3s2.3p5.4p 3P 2 | 4w | 427 |

| Ti 5 | 1864.451 | 1864.45 | 7 | 7 | 3s2.3p5.4s 3P* 2 - 3s2.3p5.4p 3D 3 | 4w | 427 |

| Ti 5 | 1881.886 | 1881.89 | 7 | 7 | 3s2.3p5.4s 1P* 1 - 3s2.3p5.4p 1P 1 | 4w | 427 |

| Ti 5 | 1920.163 | 1920.16 | 7 | 7 | 3s2.3p5.4s 3P* 1 - 3s.3p6.3d 3D 1 | 4w | 427 |

| Ti 5 | 1988.750 | 1988.75 | 7 | 7 | 3s2.3p5.4s 1P* 1 - 3s2.3p5.4p 1D 2 | 4w | 427 |

| V 4 | 678.740 | 678.74 | 60 | 60 | 3p6.3d2 3F 3 - 3p6.3d.4p 3F* 3 | 1w | 397 |

| V 4 | 679.647 | 679.65 | 50 | 50 | 3p6.3d2 3F 2 - 3p6.3d.4p 3F* 2 | 1w | 397 |

| V 4 | 693.128 | 693.13 | 50 | 50 | 3p6.3d2 3F 2 - 3p6.3d.4p 1D* 2 | 1w | 397 |

| V 4 | 2088.737 | 2088.74 | 50 | 50w | 3p6.3d.4s 3D 2 - 3p6.3d.4p 1D* 2 | 1w | 397 |

| V 4 | 2556.915 | 2556.92 | 50 | 50w | 3p6.3d.4d 1D 2 - 3p6.3d.4f 1F* 3 | 1w | 397 |

| V 5 | 239.407 | 239.41 | 16 | 16 | 3p6.3d 2D 3/2 - 3p6.5f 2F* 5/2 | 8w,7 | 432 |

| V 5 | 239.485 | 239.48 | 19 | 19 | 3p6.3d 2D 5/2 - 3p6.5f 2F* 7/2 | 8w,7 | 432 |

| V 5 | 285.9791 | 285.98 | 18 | 18 | 3p6.3d 2D 3/2 - 3p6.4f 2F* 5/2 | 10w,6,7,8 | 432 |

| V 5 | 286.8395 | 286.84 | 20 | 20 | 3p6.3d 2D 5/2 - 3p6.4f 2F* 7/2 | 10w,6,7,8 | 432 |

| V 5 | 312.394 | 312.39 | 17 | 17 | 3p6.3d 2D 5/2 - 3p5.(2P*).3d2.(1G) 2F* 7/2 | 8w,7 | 432 |

| V 5 | 483.0098 | 483.01 | 35 | 35 | 3p6.3d 2D 5/2 - 3p6.4p 2P* 3/2 | 10w,6,7,8 | 432 |

| V 5 | 484.5108 | 484.51 | 25 | 25 | 3p6.3d 2D 3/2 - 3p6.4p 2P* 1/2 | 10w,6,7,8 | 432 |

| V 5 | 820.859 | 820.86 | 20 | 20 | 3p6.4p 2P* 1/2 - 3p6.5s 2S 1/2 | 8w,1,6 | 432 |

| V 5 | 829.483 | 829.48 | 30 | 30 | 3p6.4p 2P* 3/2 - 3p6.5s 2S 1/2 | 8w,1,6 | 432 |

| V 5 | 962.031 | 962.03 | 15 | 15 | 3p6.4d 2D 5/2 - 3p5.(2P*).3d2.(3F) 2F* 7/2 | 8w,6 | 432 |

| V 5 | 1142.737 | 1142.74 | 15 | 15 | 3p6.4p 2P* 1/2 - 3p6.4d 2D 3/2 | 8w,1,6 | 432 |

| V 5 | 1157.575 | 1157.58 | 25 | 25 | 3p6.4p 2P* 3/2 - 3p6.4d 2D 5/2 | 8w,1,6 | 432 |

| V 5 | 1490.107 | 1490.11 | 20 | 20 | 3p6.4f 2F* 7/2 - 3p6.5g 2G 9/2 | 8w,6 | 432 |

| V 5 | 1680.204 | 1680.20 | 100 | 100 | 3p6.4s 2S 1/2 - 3p6.4p 2P* 3/2 | 8w,1,6 | 432 |

| V 5 | 1716.725 | 1716.72 | 50 | 50 | 3p6.4s 2S 1/2 - 3p6.4p 2P* 1/2 | 8w,1,6 | 432 |

| V 5 | 1724.994 | 1724.99 | 15 | 15 | 3p6.4d 2D 5/2 - 3p6.5p 2P* 3/2 | 8w,6 | 432 |

| V 5 | 1792.992 | 1792.99 | 25 | 25 | 3p6.4d 2D 3/2 - 3p6.4f 2F* 5/2 | 8w,6 | 432 |

| V 5 | 1811.425 | 1811.42 | 30 | 30 | 3p6.4d 2D 5/2 - 3p6.4f 2F* 7/2 | 8w,1,6 | 432 |

| V 5 | 2318.95 | 2319.66 | 20bl | 20bl | 3p6.4d 2D 3/2 - 3p5.(2P*).3d2.(1D) 2F* 5/2 | 8w,9 | 432 |

| V 5 | 2577.127 | 2577.90 | 20 | 20 | 3p6.4f 2F* 7/2 - 3p6.5d 2D 5/2 | 8w,6 | 432 |

| V 5 | 2774.997 | 2775.82 | 15 | 15 | 3p6.5p 2P* 3/2 - 3p6.5d 2D 5/2 | 8w,6 | 432 |

| V 5 | 3617.966 | 3617.97 | 15 | 15 | 3p6.5d 2D 5/2 - 3p6.6p 2P* 3/2 | 8w,6 | 432 |

| V 5 | 3746.36 | 3746.36 | 12 | 12bl | 3p6.4d 2D 5/2 - 3p5.(2P*).3d2.(1G) 2F* 7/2 | 8w,9 | 432 |

| V 5 | 4200.322 | 4200.32 | 20 | 20 | 3p6.5s 2S 1/2 - 3p6.5p 2P* 3/2 | 8w,6 | 432 |

| V 5 | 4930.533 | 4930.53 | 15* | 15w | 3p6.6h 2H* 9/2 - 3p6.7i 2I 11/2 | 8w,6 | 432 |

| V 5 | 5356.070 | 5356.07 | 8 | 8 | 3p6.6p 2P* 3/2 - 3p6.6d 2D 5/2 | 8w,6 | 432 |

| V 5 | 6628.796 | 6628.80 | 7 | 7 | 3p6.6d 2D 5/2 - 3p6.6f 2F* 7/2 | 8w | 432 |

| V 5 | 7595.511 | 7595.51 | 3* | 3 | 3p6.7h 2H* 11/2 - 3p6.8i 2I 11/2 | 8w | 432 |

+------+----------+---------+---------+---------+----------------------------------------------------------------+-----------+---------+

2.2.2. Wavelength changes in ASD

Observed wavelengths were replaced with values from Monograph 8 for 3398 lines in ASD. The lines were identified in most cases based on the match of upper and lower energy level descriptions (configuration, term, J). The previously unclassified lines were matched using the wavelengths only, as described in the previous section.

2.2.3. Transition probability changes in ASD

The A values were replaced by different ones from Monograph 8 for 1930 lines. In most cases, the difference was only in the number of significant digits, but the value itself was the same. The A value really changed only for 157 lines. The transition-probability accuracy changed for 105 lines. Of these, in 56 cases the new accuracy is ‘worse’ than the old one, and in 49 cases it is ‘better’. All changes in accuracy follow from Monograph 8.

2.2.4. Observed intensity changes in ASD

The ‘observed intensity’ value was replaced with those from Monograph 8 (sometimes corrected) for 1224 lines. Corrections to intensities in Monograph 8 are described in section 1.2.4.

2.2.5. Deleted lines in ASD

Two unclassified lines of Kr V at 496.25 and 637.87 Å are the only lines that were deleted from ASD.

2.2.6. Added lines in ASD

All lines added to ASD, 10376 in total, were taken from Monograph 8. It was verified that neither the combination of lower and upper level nor a closely lying unclassified line exist in ASD for these lines.