| Watson's Determinable Parameters |
Present Value a [MHz] |
Brown et al. [MHz] |
Ref. |
|---|---|---|---|
| A″ | 70 496.191(916) | ||
| B″ | 11 872.057(191) | ||
| C″ | 10 136.23(17) | ||
| τ1 | 0.242 59(221 58) | ||
| τ2 | 0.002 65(3299) | ||
| τ3 b | 2.2(7) | ||
| τaaaa | -7.7880(3163) | -7.75(20) | 74003 |
| τbbbb | -0.069 050(127 26) | -0.081(20) | |
| τcccc | -0.028 59(1016) | ||
| Std. dev. | 1.465 | ||
| No. lines fit | 20 | 10 | 74003 |
| Derived Parameters (assuming planarity conditions) |
|||
| A′ | 70 496.17(92) | 70 496(2) | 74003 |
| B′ | 11 872.14(17) | 11 872.24(20) | |
| C′ | 10 136.29(16) | 10 136.46(20) | |
| τ′bbcc | -0.041(11) | ||
| τ′ccaa | 0.160(67) | ||
| τ′aabb | 0.12(14) | ||
| τaabb(1) | 0.44(10) | 0.297(30) | 74003 |
| τaabb(2) | 0.39(12) | ||
| τaabb(3) | 0.39(12) | ||
| τabab(1) | -0.159(23) | -0.126(60) | |
| τabab(2) | -0.111(56) | ||
| τabab(3) | -0.104(04) | ||
| Δτ | |||
a The uncertainties quoted are one standared deviation as estimated by the least squares fit. The number of significant figures quoted are necessary to reproduce the calculated transition frequencies within their standard deviations.b Strictly speaking, τ3 is not a determinable parameter, but is calculated from τ1, τ2, τaaaa, and τbbbb using the planarity conditions.
| Parameter | Value | Parameter | Value | Ref. |
|---|---|---|---|---|
| As | -951.79(10) | χaa | 5.59(10) | 74003 |
| Bs | -92.86(10) | χbb | -0.73(10) | |
| Cs | 4.49(10) | χcc | -4.86(10) | |
| AF | 164.39(40) | AN | 46.57(10) | |
| Taa (F) | -241.75(40) | Taa (N) | -47.72(10) | |
| Tbb (F) | -226.48(40) | Tbb (N) | -50.47(10) | |
| Tcc (F) | 468.22(40) | Tcc (N) | 98.19(10) | |
| Electric dipole moment | ||||
| µb [C · m] µb [D] |
0.136(10) |
74003 | ||
