NO2

Rotational and centrifugal distortion constants

Parameter 14N16O2 Value a
[MHz]
15N16O2 Value
[MHz]
14N16O18O Value
[MHz]
Ref.
A 239 868.7(110) 228 756.1(40) 235 802.5(150) 64008
B 13 000.12(60) 13 003.06(20) 12 264.92(80)
C 12 303.45(60) 12 274.73(20) 11 632.71(80)
τaaaa -299.4(4) -273.4(40) -284.4(40)
τbbbb -0.041 44(15) -0.041 44(15) -0.037 21(15)
τaabb 1.843(20) 1.761(20) 1.705(20)
τabab -0.2453(10) -0.2445(10) -0.2188(10)
µb [C · m]
     µb [D]
1.054(33) × 10-30 
     0.316(10) b
0.981(50) × 10-30 
     0.294(15) c
 

 
a See table below for constants derived from infrared and microwave spectra.
 
b Reference [63009].
 
c Reference [64009].

 

Spin-rotation and hyperfine constants for NO2

Parameters 14N16O2
Value a
[MHz]
14N16O2
υ2=1 Value b
[MHz]
15N16O2
Value a
[MHz]
14N16O18O
Value c
[MHz]
14N16O17O
Value d
[MHz]
Ref. 66026 76019 66026 64008 66025
As 5401.76(7) 5920.4(13) 5149.07(10) 5326.08(460) 5369.58(250)
Bs 7.65(2) 6.4(3) 7.70(3) 7.72(5) 8.05(260)
Cs -95.24(2) -97.1(3) -94.99(10) -90.58(6) -92.92(90)
(O)I (14N or 15N) 147.23(3) 147.0(2) -206.46(6) 146.62(60) 147.28(5)
(aa)I (14N or 15N) -22.16(7) -22.2(4) 30.89(20) -19.92(220) -21.93(14)
(cc)I (14N or 15N) -17.69(8) -18.1(4) 25.11(20) -18.85(130) -17.00(24)
(aa)Q (14N) 0.45(6) 0.45 a   1.69(120) 0.41(8)
(cc)Q (14N) 1. 26(5) 1.26 a   0.92(60) 1.33(15)
(O)I (17O)   -63.76(3)
(aa)I (17O) 50.48(8)
(cc)I (17O) 55.85(10)
(aa)Q (17O) -0.202(14)
(cc)Q (17O) -0.009(16)

a Assumed value.

b Additional references: [50018], [51014], [58004], [59010], [62003], [62004], [72042], [72043], [73049], [73065], [74008], [74016], [74017], [74018], [74019], [74020], [74023], [75015], [75016], [75027], [75028], [75029].

 

Rotational constants for 14NO2 ground state and (0,1,0) state from combined infrared and microwave spectra.

Parameters Ground State Value
[MHz]
Ref. (0,1,0) State Value
[MHz]
Ref.
script A 239 905.41(63) 76020 a 251 027.(23) 75036 b
script B 13 002.262(123) 13 000.13(234)
script C 12 304.888(66) 12 278.87(192)
ΔK 80.94(39) 101.45(183)
ΔNK -0.5903(90) -0.668(35)
ΔN 9.033(90) x 10-3 9.033(90) x 10-3
δK 0.12(5) 0.12(5)
δN 9.303(288) x 10-4 9.303(288) x 10-4
HK 0.0977(138) 0.0977(138)
HKN -7.26(165) x 10-4 -7.26(165) x 10-4
HN 1.6(18) x 10-8 1.6(18) x 10-8
LK 1.7(12) x 10-4 1.7(12) x 10-4)

a See [76020] for molecular constants for υ3=1 also.

b The change in parameters between the ground state and υ2=1 are reported. These changes are significant only for the values of script A, scriptB, scriptC, ΔK, and ΔNK when compared to the uncertainty in the ground state constants.


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