ClNO Spectral Data Options

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Display the following isotopes:

Formula   (# of lines)
35Cl14N16O    (101)
37Cl14N16O    (49)
35Cl14N18O    (22)
Total:      (172)

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 Isotope   Relative
Atomic Mass
 
   Isotopic
  Composition  
Standard
Atomic Weight
 
 Notes 
 
7 N 14   14.003 074 004 43(20)   0.996 36(20)  [14.006 43, 14.007 28]  
15   15.000 108 898 88(64)   0.003 64(20)

8 O 16   15.994 914 619 57(17)   0.997 57(16)  [15.999 03, 15.999 77]  
17   16.999 131 756 50(69)   0.000 38(1)
18   17.999 159 612 86(76)   0.002 05(14)

17 Cl 35   34.968 852 682(37)   0.7576(10)  [35.446, 35.457] m
37   36.965 902 602(55)   0.2424(10)

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Constants Data for ClNO
References for ClNO
NIST Chemistry Webbook Search for ClNO

Specific Corrections and Reanalysis of the Data:

In the reanalysis of 35ClNO, two measured lines were excluded from the fit since they show significant deviations. The 109,2-99,1 transition reported in [66012] at 111 213.25 MHz is calculated 1.48 MHz higher in frequency with an uncertainty of 0.14 MHz and the 180,18-170,17 line reported in [66012] at 198 798.54 MHz is calculated 15.62 MHz lower in frequency with an uncertainty of 0.18 MHz. The error in the 41,3-40,4 transition frequency reported in [75010] has been corrected to read 83 635.88 MHz. Very poor agreement was obtained in the centrifugal distortion fit to the 20,2-10,1 transition and hyperfine splittings for 37ClNO. The strongest components, the unresolved pair F = 7/2-5/2 and F=5/2-3/2, are calculated 0.80 MHz higher than observed and the F = 3/2-3/2 transition is calculated 1.32 MHz higher than observed. The hyperfine analysis included the three components of the 10,1-00,0 transition and the three unblended components of the 21,2­11,1 and 21,1­11,0 transitions. The discrepancy could arise from ignoring the 14N hyperfine splitting, although this appears unlikely since these splittings were apparently unresolved.


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