FNO Spectral Data Options

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Display the following isotopes:

Formula   (# of lines)
19F14N16O    (129)
19F15N16O    (6)
19F14N18O    (14)
Total:      (149)

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The following information may be useful
in choosing which isotopes to search.

 Isotope   Relative
Atomic Mass
 
   Isotopic
  Composition  
Standard
Atomic Weight
 
 Notes 
 
7 N 14 14.003 074 005 2(9)   99.632(7) 14.0067(2) g,r,e
15 15.000 108 898 4(9)   0.368(7)

8 O 16 15.994 914 6221(15)   99.757(16) 15.9994(3) g,r
17 16.999 131 50(22)   0.038(1)
18 17.999 160 4(9)   0.205(14)

9 F 19 18.998 403 20(7)   100 18.998 403 2(5)  

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Constants Data for FNO
References for FNO
NIST Chemistry Webbook Search for FNO

Specific Corrections and Reanalysis of the Data:

One transition was not included in the P 6 centrifugal distortion analysis since it shows a large deviation from the calculated value. In particular, the 142,12-151,15 transition is calculated at 27 632.73(30) MHz but is reported 2.15 MHz higher in frequency. Several other transitions listed below show fairly large Deltanu(obs-calc):

Transition   Deltanu(obs-calc) MHz

182,16-173,15     0.486
122,10-171,13     0.481
  80,8-71,7   -0.449
  85,4-75,3     0.640
  73,5-63,4     0.696
  71,6-61,5     0.436
  75,3-65,2   -0.430
  50,5-41,4   -0.606

Based on the students t test, which ranged from 2 to 3 for these lines they could not be excluded but the measurement accuracy is questionable in these cases.


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