Parameter a | (000) State | Ref. | (010) State | Ref. |
---|---|---|---|---|
963.09866(41) | 82033 | |||
73.05775(11) | 82034 | 184.122 63(82) | ||
8.415 172(76) | 8.362 16(15) | |||
7.219 272(45) | 7.092 84(20) | |||
1.991 049(47) | 23.969 b | |||
-0.019 660(27) | -0.078 89(14) | |||
0.000 301 3(34) | 0.000 162(18) | |||
0.0 | 1.52 b | |||
-0.001 941 7(21) | 0.0 | |||
0.0 | ||||
0.778 42(14) | 0.795 60(48) | |||
0.039 906(38) | 0.035 40(53) | |||
0.000 446(78) | 0.003 52(54) | |||
-0.005 148(18) | -0.004 70(23) | |||
-0.004 106(27) | -0.004 58(21) | |||
-20.26(51) | ||||
39.7(17) | ||||
-20.2(19) |
a Parameters not given were fixed at zero. The numbers in parentheses are one standard deviation from the least-squares fit in units of the last quoted digit.
b ΔK and ΦK were fixed at values determined from the semi-rigid bender model.
c δN was fixed at its ground (000) state value.
Parameter a | (000) State | (010) State | Ref. |
---|---|---|---|
959.1674(2) | 83049 | ||
72.627 b | 181.234 23(143) | ||
8.415 767(67) | 8.370 93(76) | ||
7.208 087(390) | 7.076 65(73) | ||
2.583 b | 23.657 b | ||
-0.019 66 c | -0.078 89 c | ||
0.127 b | 1.50 b | ||
0 | |||
0 | |||
0.780 05(130) | 0.797 67(37) | ||
0.041 76(53) | 0.038 39(137) | ||
a Parameters not given were fixed at zero. The numbers in parentheses are one standard deviation from the least-squares fit in units of the last quoted digit.
b These parameters were fixed at values determined from a fit to non-rigid bender calculations for 13CH2 by Jensen et al. [82032].
c These parameters were fixed to 12CH2 values.
Parameter | (000) State a | (010) State b | Ref. |
---|---|---|---|
752.3795(4) | 84028 | ||
37.786 829(60) | 70.455 24(38) | ||
3.962 159(12) | 3.930 017(27) | ||
0.267 57(10) | 0.3029(46) | ||
0.560 228(16) | 4.991 843(60) | ||
-0.019 590(62) | |||
0.0196 c | 0.278 c | ||
0 e | 0 e | ||
0.776 466(93) | 0.789 35(24) | ||
0.040 580(65) | 0.037 27(24) | ||
a From a fit to the previous far-infrared LRM data [83050] with the addition of the measurements of the523 ← 514 transition.
b From a fit to ν2-band diode-laser measurements [83055] and the data of [84028]. For both states, magnetic g values were fixed at theoretical values, and the numbers in parentheses are one standard deviation from the least-squares fit expressed units of the last quoted digit.
c Fixed at a value determined from the energy levels given by Bunker and Jensen [83048].
d Fixed at the ground-state value.
e This parameter and all others not listed were fixed at zero.