| Watson's Determinable Parameters |
35Cl14N16O Value a [MHz] |
37Cl14N16O Value a [MHz] |
Deprived Parameters b |
35Cl14N16O Value a [MHz] |
37Cl14N16O Valuea [MHz] |
|---|---|---|---|---|---|
| A″ | 87 374.608(96) | 87 207(66) c | A′ | 87 374.596(96) | 87 207(66) |
| B″ | 5737.6537(53) | 5601.217(33) | B′ | 5737.757(11) | 5601.18(25) |
| C″ | 5376.2712(55) | 5255.947(34) | C′ | 5376.261(16) | 5256.08(26) |
| τ1 | 0.1605(6) | 0.1566(35) | τ′bbcc | -0.024 71(14) | -0.0246(11) |
| τ2 | -0.011 06(24) | -0.0124(28) | τ′ccaa | 0.206(28) | |
| τ3 d | 7.01(3) | 6.59(88) | τ′aabb | -0.021(28) | |
| τaaaa | -17.23(13) | c | τaabb(1) | 0.310(32) | |
| τbbbb | -0.029 426(40) | -0.027 50(121) | τaabb(2) | 0.239(16) | |
| τcccc | -0.021 446(107) | -0.020 40(95) | τaabb(3) | 0.239(16) | |
| χaa(Cl) | -49.69(33) | -39.02(37) | τabab(1) | -0.166(30) | |
| χbb(Cl) | 29.96(53) | 23.47(57) | τabab(2) | -0.099(15) | |
| χcc(Cl) | 19. 73(53) | 15. 55(57) | τabab(3) | -0.094(18) | |
| Std. dev. | 0.197 | 0.350 | Δτ | 0.0016(36) | |
| No. lines | 44 | 34 |
a The uncertainties quoted are one standard deviation as estimated by the least squares fit. the number of significant figures quoted are necessary to reproduce the calculated ransition frequencies within their standard deviations.b Assuming planarity conditions.
c Since A″ and τaaaa are directly correlated, τaaaa had to be fixed at zero in this analysis.
d Strictuly speaking, τ3 is not a determinable parameter, but is calculated from τ1, τ2, τaaaa, and τbbbb using the planarity conditions.
| Isotopic Species |
Vib. State υ1 υ2ℓ υ3 |
A [MHz] |
B [MHz] |
C [MHz] |
|
|---|---|---|---|---|---|
| 35Cl14N16O | 0 0 0 | 87 374.43(3) | 5737.72(1) | 5376.27(1) | 75010 |
| 0 1 0 | 88 147(46) | 5715.70(2) | 5348.16(2) | ||
| 0 0 1 | 87 879.64(30) | 5710.53(5) | 5349.19(3) | ||
| 37Cl14N16O | 0 0 0 | 5601.25(4) | 5255.99(4) | 65007 | |
| 35Cl14N18O | 5439.31(40) | 5103.17(40) | 61005 |
a Additional references: [50015], [61004], and [75014].
| Isotopic Species |
χaa(Cl) [MHz] |
χbb(Cl) [MHz] |
χaa(N) [MHz] |
χbb(N) [MHz] |
µa | Ref. |
|---|---|---|---|---|---|---|
| 35Cl14N16O | -49.18(35) | 29.46(20) | 1.0(4) | -4.8(2) | ||
| 37Cl14N16O | -38.89(40) | 22.97(30) | 1.0(4) | -4.8(2) | ||
| 35Cl14N18O | -48.8 c |
| a Reference
[51005]. b The values in the table are taken from this reference unless otherwise indicated. c Reference [61005]. |
