Parameters | H216O Value [MHz] |
Ref. | H217O Value a [MHz] |
Ref. | H218O Value [MHz] |
Ref. |
---|---|---|---|---|---|---|
835 840.288(1000) | 74005 b | 830 282.838 ± 8.7 | 75009 | 825 366.08 ± 8.7 | 74005 c | |
435 351.717(900) | 435 341.662 ± 8.0 | 435 331.59 ± 8.0 | ||||
278 138.700(900) | 277 510.396 ± 8.0 | 276 950.46 ± 8.0 | ||||
ΔJ | 37.594 22 ± 0.049 | 37.444 01 | 37.2938 ± 0.30 | |||
ΔJK | -172.9128 ± 0.34 | -171.5584 | -170.204 ± 1.3 | |||
ΔK | 973.290 52 ± 0.19 | 965.7665 ± 2.3 | 959.6441 ± 2.3 | |||
δJ | 15.210 402 ± 0.020 | 15.226 75 | 15.2431 ± 0.21 | |||
δK | 41.0502 ± 0.30 | 36.2566 | 31.463 ± 1.2 | |||
HJ | ||||||
HJK | ||||||
HKJ | ||||||
HK | 3.733 028 ± 0.015 | 4.409 069 | 5.085 11 ± 0.24 | |||
hJ | ||||||
hJK | ||||||
hK | 1.0971 ± 0.052 | |||||
LJK | ||||||
LKKJ | ||||||
LK | ||||||
ℓK | ||||||
PK | ||||||
pK |
a All distortion constants except ΔK were calculated from H216O and H218O constants. |
Parameters | HDO Value [MHz] |
Ref. | HTO Value [MHz] |
Ref. |
---|---|---|---|---|
701 931.502 ± 0.22 | 74005 a | 677 849.040 ± 0.17 | 74037 | |
272 912.599 ± 0.11 | 198 197.489 ± 0.128 | |||
192 055.245 ± 0.10 | 150 462.412 ± 0.128 | |||
ΔJ | 10.837 49 ± 0.0058 | 5.212 023 ± 0.003 | ||
ΔJK | 34.207 29 ± 0.037 | 48.522 76 ± 0.02 | ||
ΔK | 377.078 28 ± 0.026 | 271.275 33 ± 0.06 | ||
δJ | 3.647 126 ± 0.0014 | 1.414 126 ± 0.0005 | ||
δK | 63.087 50 ± 0.035 | 51.328 33 ± 0.07 | ||
HJ | ||||
HJK | ||||
HKJ | ||||
HK | 1.465 159 ± 0.0027 | 0.896 3777 ± 0.011 | ||
hJ | ||||
hJK | ||||
hK | ||||
LJ | ||||
LJK | ||||
LKKJ | ||||
LK | ||||
ℓKJ | ||||
ℓK | ||||
PK | ||||
pK |
Parameters | DTO Value [MHz] |
Ref. | T2O Value [MHz] |
Ref. |
---|---|---|---|---|
410 174.145 ± 0.078 | 74037 | 338 810.923 ± 0.076 | 73058 | |
172 101.952 ± 0.045 | 145 665.417 ± 0.044 | |||
119 127.850 ± 0.045 | 100 259.415 ± 0.044 | |||
ΔJ | 5.199 034 ± 0.003 | 4.145 597 ± 0.0014 | ||
ΔJK | -15.504 11 ± 0.015 | 22.038 98 ± 0.008 | ||
ΔK | 180.310 52 ± 0.010 | 144.137 66 ± 0.006 | ||
δJ | 1.941 256 ± 0.0010 | 1.609 823 ± 0.0008 | ||
δK | 12.8893 ± 0.012 | 5.440 92 ± 0.01 | ||
HJ | ||||
HJK | ||||
HKJ | ||||
HK | ||||
hJ | ||||
hJK | ||||
hK | ||||
LJJK | ||||
LKKJ | ||||
LJK | ||||
LK | ||||
ℓJ | ||||
ℓK | ||||
ℓJK | ||||
PJJK | ||||
PKJ | ||||
PK | ||||
pK | ||||
pKKJ |
Parameters | D216O (0, 0, 0) State [MHz] |
D216O (0, 1, 0) State [MHz] |
Ref. |
---|---|---|---|
462 278.854(52) | 498 730(24) | 73057 | |
218 038.233(33) | 220 039(14) | ||
145 258.022(21) | 143 611(6) | ||
τ′xxxx | -66.654(11) | -74.1(7) | |
τ′yyyy | -7.650(4) | -7.67(24) | |
τ′zzzz | -963.936(68) | -1491.2(37) | |
τ1′ | 71.429(76) | 101.0(32) | |
τ2′ | -51.107(79) | -17.5(56) | |
HJ | |||
HJK | |||
HKJ | |||
HK | 1.05(3) | ||
hJ | |||
hJK | |||
hK | |||
GKJK | |||
GKJ | |||
GK | |||
gK | |||
F2 | |||
F3 | |||
F5 | |||
Kivelson-Wilson Rotational Constants | |||
A | 462 291.698 | 498 746 | 73057 |
B | 217 982.286 | 219 960 | |
C | 145 301.126 | 143 672 |
Parameters | D217O Value a [MHz] |
D218O Value a [MHz] |
Ref. |
---|---|---|---|
456 766.850(250) | 451 891.921(530) | 73056 | |
218 041.011(160) | 218 045.181(280) | ||
144 701.487(58) | 144 201.681(140) | ||
τ′xxxx | -66.219(44) | -66.653(83) | |
τ′yyyy | -7.405(18) | -7.537(45) | |
τ′zzzz | -938.124(240) | -920.459(50) | |
τ1′ | 72.050(270) | 67.238(550) | |
τ2′ | -47.660(280) | -49.030(570) | |
HJ | |||
HJK | |||
HKJ | |||
HK | 0.536 55(35) | 0.517 73(77) | |
2hJ | |||
hJK | |||
hK | 0.116 36(63) | 0.10905(150) | |
GKJK | |||
GKJ | |||
GK | |||
gK | |||
F2 | |||
F3 | |||
F5 | |||
Kivelson-Wilson Rotational Constants | |||
A | 456 779.808 | 451 905.017 | 73056 |
B | 217 985.875 | 217 990.613 | |
C | 144 743.666 | 144 243.154 |
a In cases where no uncertainties are indicated the
values were fixed at those obtained for D216O.
Parameters | HD18O Value [MHz] |
Ref. | HD16O (0,1,0) state [MHz] |
Ref. |
---|---|---|---|---|
692 872.91(879) | 70059 | 764 781(48) | 71035 | |
271 598.61(201) | 276 856(16 | |||
190 714.17(280) | 189 567(14) | |||
τ′xxxx | -70.04(24) | -81.66(50) | ||
τ′yyyy | -13.043(220) | -12.85(40) | ||
τ′zzzz | -1599.58(275) | -2953.0(93) | ||
τ1′ | -268.61(265) | -265.5(35) | ||
τ2′ | -115.86(357) | -49.2(37) | ||
HJ | 0.001 61(49) | |||
HJK | 0.0516(42) | |||
HK | 0.582(72) | 3.22(11) | ||
2hJ | 0.000 88(20) | |||
hJK | 0.0666(66) | |||
hK | 0.225(30) | |||
GJK | 0.0103(13) | -0.0156(15) | ||
Kivelson-Wilson Rotational Constants | ||||
A | 692 883.9 | 70059 | 764 798 | 71035 |
B | 271 530.5 | 276 745 | ||
C | 190 771.3 | 189 662 |
Isotopic Species |
Rotational State |
eQq (D) [kHz] | c (D) [kHz] | c (H) [kHz] | Ref. |
---|---|---|---|---|---|
H216O | 616 | -32.70 a | 67014 | ||
523 | -31.75 a | ||||
HD16O | 220 | 80.10(3) | -2.07(1) | -42.38(2) | 67023 |
221 | 79.16(3) | -2.04(1) | -43.23(3) | ||
743 | -15.65(20) | -3.16(3) | -26.15(5) | 68014 | |
744 | -15.65(20) | -3.16(3) | -26.15(5) | ||
D2O | 313 | -72.92(2) | -2.62(1) | 67023 | |
220 | 49.57(2) | -2.80(1) | |||
441 | 78.5(1) | -2.86(3) | 68014 | ||
532 | 8.3(1) | -2.60(2) |
a Kukolich
[69033] obtained the
following values
|
Isotopic Species |
Atom | χaa [kHz] |
χbb [kHz] |
χcc [kHz] |
Maa [kHz] |
Mbb [kHz] |
Mcc [kHz] |
Ref. |
---|---|---|---|---|---|---|---|---|
H216O | H | -35.14(15) | -30.68(30) | -32.68(16) | 67024 | |||
HD16O | H | -56.81(30) | -8.80(8) | -23.28(10) | ||||
D | -1.07(1) | -4.32(4) | -3.57(2) | |||||
D216O | D | 307.91(14) a | -133.13(14) a | -174.78(20) a | -2.99(1) | -2.36(2) | -2.64(1) | 67024, 67023 |
H217O | 17O | -8899. | -1269. | 10 169. | 75009 | |||
HD17O | 17O | -7877.8 | -2229. | 10 106.8 | 73056, 69031 | |||
D217O b | 17O | -8896.4 | -1210.4 | 10 106.8 | 73056 |
a These quadrupole tensor components are along an axis system defined by P.W. Posener [Aust. J. Phys. 13, 168 (1960)] with the aa direction close to the OD bond direction.b Calculated from the HD17O values.
Parameters | H216O Value | HD16O Value | D216O Value | Ref. |
---|---|---|---|---|
µa [D] |
0.6567(4) |
73059 | ||
µb [D] |
1.8546(4) |
1.7318(9) |
1.8545(4) |
73059, 73060 |
gaa (µN) | 0.6650(20) | 0.623 a | 0.3233(10) | 69033 |
gbb (µN) | 0.7145(20) | 0.408 a | 0.3580(10) | |
gcc (µN) | 0.6465(20) | 0.438 a | 0.3226(10) | |
b Units are erg/G2 · mol.
Microwave Spectrum | Stark Effect |
Zeeman Effect |
Hyperfine Structure |
Pressure Broadening Line Width |
Other | |
---|---|---|---|---|---|---|
46001 46002 46003 47006 49010 53013 53014 53016 53018 |
54006 54012 55011 66030 66031 70053 71005 74043 |
48010 72051 72052 75008 |
49011 51008 51009 63020 65021 69035 |
59014 60006 64020 |
65022 69030 69032 69034 69051 71027 |
54011 62003 67025 69052 69053 70054 |