HBS

Rotational Constants

Isotropic
Species		 Vibrational
State
υ1 υ2ℓ υ3		 Bυ
[MHz]		 Dυ
[MHz]		 qυ
[MHz]		 Ref.
H11B32S 0 00 0 19 083.006(4) 0.021 89(4)   73027
1 00 0 18 994.33(42) a    
0 11 0 19 106.472(20) 0.0219 b 46.45(1)
H10B32S 0 00 0 20 080.234(9) 0.024 22(9)  
1 00 0 19 979.0(12) a    
0 11 0 20 108.482(30) 0.0240 b 50.80(5)
H11B34S 0 00 0 18 791.623(10) 0.021 25(10)  
1 00 0 18 704.4(12) a    
H10B34S 0 00 0 19 793.168(15) 0.023 18(25)  
1 00 0 19 693.5(18) a    
D11B32S 0 00 0 15 937.934(7) 0.014 25(4)  
0 11 0 15 970.719(20) 0.0143 b 40.65(6)
D10B32S 0 00 0 16 563.378(11) 0.015 61(6)  
0 11 0 16 600.733(30) 0.0156 b 43.16(2)
D11B34S 0 00 0 15 686.936(12) 0.014 02(8)  
D10B34S 0 00 0 16 317.465(18) 0.01497(14)  

a Calculated from ΔB = B′ - B″ given by Sams and Maki [75013].

b The ground state value of Dυ was assumed to derive Bν from the data in Ref. [73027]. The Bυ values given may not represent the true value due to a lack of information on the possible Fermi resonance between the (0,20,0) and (0,00,1) excited states.

 

 

Hyperfine and Zeeman Constants and Electric Dipole Moment for HBS
Parameter Value Zeeman Constants H11B32S D11B32S Ref.
eQq (11B) -3.72(3) [MHz] g⊥ (µN) -0.0414(2) -0.0356(2) 74039
eQq (10B) -7.91(3) [MHz] χ⊥ - χ|| [erg/G2 · mol] 7.2(5) x 10-6 9.8(21) x 10-6
M⊥ (11B) -7.2(30) [kHz] Q|| [esu · cm2] 2.7(6) x 10-26  
M⊥ (10B) -2.6(10) [kHz]      
µ0 [C · m]
     µ0 [D]		 4.330(17) x 10-30 
     1.298(5)		      

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