| Watson's Determinable Parameters |
Valuea this work [MHz] |
Value | Ref. |
|---|---|---|---|
| A″ | 41 723.36(14) | 41 723.34(16) | 72045 |
| B″ | 4114.1091(238) | 4114.154(26) | |
| C″ | 3738.5576(225) | 3738.605(21) | |
| τ1 | 0.1986(314) | ||
| τ2 | |||
| τ3 b | 0.9(2) | ||
| τaaaa | -7.071(284) | -6.99(30) | |
| τbbbb | -0.010 74(110) | -0.0110(13) | |
| τcccc | |||
| Std. dev. | 0.364 c | ||
| No. lines | 28 | ||
Derived Parameters |
|||
| A′ | 41 723.36(14) | 72045 | |
| B′ | 4114.140(34) | ||
| C′ | 3738.630(50) | ||
| τ′bbcc | -0.00772(92) | ||
| τ′ccaa | 0.061(53) | ||
| τ′aabb | 0.145(69) | ||
| τaabb(1) | 0.144(62) | 0.176(14) | |
| τaabb(2) | 0.183(20) | ||
| τaabb(3) | 0.183(20) | ||
| τabab(1) | 0.0008(638) | -0.0334(68) | |
| τabab(2) | -0.0356(95) | ||
| τabab(3) | -0.0389(153) | ||
| Δτ | |||
a The uncertainties quoted are one standard deviation as estimated by the least squares fit. The number of significant figures quoted are necessary to reproduce the calculated transition frequencies within their standard deviations.
b Strictly speaking, τ3 is not a determinable parameter, but is calculated from τ1, τ2, τaaaa, and τbbbb using the planarity conditions.
c Convergence was relatively slow and the 51,4-50,5 deviates by -0.87 MHz as found in [72045]
|
Isotopic Species |
Vib. State υ1 υ2 υ3 |
A [MHz] |
B [MHz] |
C [MHz] |
χaa(Cl) [MHz] |
χbb(Cl) [MHz] |
χcc(Cl) [MHz] |
Ref. |
|---|---|---|---|---|---|---|---|---|
| 14N32S35Cl | 0 0 0 | 41 723.36 a | 4 114.109 a | 3 738. 558 a | -39.1 | 23.8 | 15.3 | 70021 |
| 0 1 0 | 41 835.87 | 4097.62 | 3722.47 | |||||
| 0 0 1 | 42 436.12 | 4 104.81 | 3 726.52 | |||||
| 14N32S37Cl | 0 0 0 | 41 623.10 | 3997.51 | 3641.10 | ||||
| 14N34S35Cl | 0 0 0 | 40 583.07 | 4079.15 | 3700.26 | ||||
| 15N32S35Cl | 0 0 0 | 40 355.96 | 4019.65 | 3649.36 | -38.51 | 23.51 | 15.00 | |
| Electric dipole moment for 15N32S35Cl | ||||||||
µa [D] |
0.5645(85) |
72045 | ||||||
µb [D] |
1.747(35) |
|||||||
