Watson's Determinable Parameters |
14N32S19F a [MHz] |
Ref. | 14N34S19F a [MHz] |
Ref. |
---|---|---|---|---|
A″ | 49 719.6068(172) | 72031 | 48 298.98 | 67013 |
B″ | 8 712.258 90(316) | 8701.26 | ||
C″ | 7392.998 08(269) | 7352.78 | ||
τ1 | 0.377 175 0(273 83) | |||
τ2 | 0.025 408 1(4089) | |||
τ3 b | 1.276(9) | |||
τaaaa | -8.896 917(3700) | -8.467 07 | 67013 | |
τbbbb | -0.056 255 26(151 69) | -0.057 13 | ||
τcccc | -0.019 434 3(1098) | |||
HJ | ||||
HJK | ||||
HKJ | ||||
HK | ||||
hJ c | ||||
hJK | ||||
hK | ||||
Std. dev. | 0.047 | |||
No. lines fit | 76 | |||
Derived Parameters (assuming planarity conditions) |
||||
A′ | 49 719.592(17) | 72031 | ||
B′ | 8712.324(3) | |||
C′ | 7393.137(3) | |||
τ′bbcc | -0.030 43(13) | |||
τ′ccaa | 0.1303(7) | |||
τ′aabb | 0.2773(19) | |||
τaabb(1) | 0.4572(11) | 0.429 93 | 67013 | |
τaabb(2) | 0.4469(10) | |||
τaabb(3) | 0.4469(10) | |||
τabab(1) | -0.089 96(40) | 0.083 46 | ||
τabab(2) | -0.081 00(53) | |||
τabab(3) | -0.079 67(56) | |||
Δτ | -0.335(9) |
a The uncertainties quoted are one standared deviation as estimated by the least squares fit. The number of significant figures quoted are necessary to reproduce the calculated transition frequencies within their standard deviations.b Strictly speaking, τ3 is not a determinable parameter, but is calculated from τ1, τ2, τaaaa, and τbbbb using the planarity conditions.
c Watson uses 2hJ for this parameter.
Parameter | Value | Ref. |
---|---|---|
χaa (14N) [MHz] | -1.720(41) | This work |
χbb (14N) [MHz] | -3.990(36) | |
χcc (14N) [MHz] | 5.710(46) | |
µa [C · m] µa [D] |
0.242(12) |
67013 |
µb [D] |
1.886(11) |