S2O

Rotational and Centrifugal Distortion Constants for 32S216O

Watson's
Determinable
Parameters
32S216O (0,0,0) a,b
[MHz]
32S216O (0,1,0) a
[MHz]
Derived
Parameters c
32S216O (0,0,0) b
[MHz]
32S216O (0,1,0)
[MHz]
A 41 915.4395(100) 42 479.687(24) A 41 915.436(10) 42 479.683(24)
B 5059.047 06(131) 5059.735 51(471) B 5059.0714(13) 5059.7598(43)
C 4507.157 63(131) 4500.8588(42) C 4507.1896(12) 4500.8870(36)
τ1 0.105 983(308) 0.097 785(3959) τbbcc -0.006 688(13) -0.007 17(15)
τ2 0.004 940 26(3709) 0.003 748(464) τccaa 0.048 65(11) 0.0486(12)
τ3 d 0.601(1) 0.66(2) τaabb 0.064 02(23) 0.0564(51)
τaaaa -4.679 33(269) -5.0330(170) τaabb (1) 0.130 13(16) 0.1349(17)

τbbbb

-0.010 3185(152) -0.010 957(175) τaabb (2) 0.129 06(50) 0.1171(52)
τcccc -0.004 7746(166) -0.005 489(187) τaabb (3) 0.129 06(50) 0.1171(52)
HJ -0.7367(4840) x 10-8   τabab (1) -0.033 06(11) -0.0393(13)
HJK 0.2400(1321) x 10-6   τabab (2) -0.032 09(39) -0.0232(39)
HKJ -0.6155(1234) x 10-5   τabab (3) -0.031 99(43) -0.0214(44)
HK 0.1349(258) x 10-3        
hJ e 0.418(157) x 10-8   Δτ -0.199(83) x 10-4 -0.33(10) x 10-3
hJK -0.546(292) x 10-6        
hK 0.3578(1459) x 10-4        
Std. dev. 0.074 0.069      
No. lines fit 113 22      
µa [C · m]
     µa [D]
2.92(3) x 10-30 
     0.875(10) f
       
µb [C · m]
     µb [D]
3.94(7) x 10-30 
     1.18(2) f
       

a The uncertainties quoted are one standard deviation as estimated by the least squares fit. The number of significant figures quoted are necessary to reproduce the calculated transition frequencies within their standard deviations.

b Data from [73041] and [74006] shown in the Microwave spectrum of S2O was refit to obtain these values.

c Assuming planarity conditions.

d Strictly speaking, τ3 is not a determinable parameter, but is calculated from τ1, τ2, τaaaa, and τbbbb using the planarity conditions.

e Watson uses 2hJ for this parameter.

f Reference [59003]

 

Rotational Constants
for 34S32S16O and 32S34S16O

Rotational
Constant
34S32S16O
[MHz]
32S34S16O
[MHz]
Ref.
A 41 737.142(60) 40 637.232(75) 74006
B 4901.545(10) 5034.435(10)
C 4379.740(10) 4472.449(10)


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