Watson's Determinable Parameters |
32S216O (0,0,0) a,b [MHz] |
32S216O (0,1,0) a [MHz] |
Derived Parameters c |
32S216O (0,0,0) b [MHz] |
32S216O (0,1,0) [MHz] |
---|---|---|---|---|---|
A″ | 41 915.4395(100) | 42 479.687(24) | A′ | 41 915.436(10) | 42 479.683(24) |
B″ | 5059.047 06(131) | 5059.735 51(471) | B′ | 5059.0714(13) | 5059.7598(43) |
C″ | 4507.157 63(131) | 4500.8588(42) | C′ | 4507.1896(12) | 4500.8870(36) |
τ1 | 0.105 983(308) | 0.097 785(3959) | τ′bbcc | -0.006 688(13) | -0.007 17(15) |
τ2 | 0.004 940 26(3709) | 0.003 748(464) | τ′ccaa | 0.048 65(11) | 0.0486(12) |
τ3 d | 0.601(1) | 0.66(2) | τ′aabb | 0.064 02(23) | 0.0564(51) |
τaaaa | -4.679 33(269) | -5.0330(170) | τaabb (1) | 0.130 13(16) | 0.1349(17) |
τbbbb |
-0.010 3185(152) | -0.010 957(175) | τaabb (2) | 0.129 06(50) | 0.1171(52) |
τcccc | -0.004 7746(166) | -0.005 489(187) | τaabb (3) | 0.129 06(50) | 0.1171(52) |
HJ | τabab (1) | -0.033 06(11) | -0.0393(13) | ||
HJK | τabab (2) | -0.032 09(39) | -0.0232(39) | ||
HKJ | τabab (3) | -0.031 99(43) | -0.0214(44) | ||
HK | |||||
hJ e | Δτ | ||||
hJK | |||||
hK | |||||
Std. dev. | 0.074 | 0.069 | |||
No. lines fit | 113 | 22 | |||
µa [D] |
0.875(10) f |
||||
µb [D] |
1.18(2) f |
a The uncertainties quoted are one standard deviation as estimated by the least squares fit. The number of significant figures quoted are necessary to reproduce the calculated transition frequencies within their standard deviations.b Data from [73041] and [74006] shown in the Microwave spectrum of S2O was refit to obtain these values.
c Assuming planarity conditions.
d Strictly speaking, τ3 is not a determinable parameter, but is calculated from τ1, τ2, τaaaa, and τbbbb using the planarity conditions.
e Watson uses 2hJ for this parameter.
Rotational Constant |
34S32S16O [MHz] |
32S34S16O [MHz] |
Ref. |
---|---|---|---|
A″ | 41 737.142(60) | 40 637.232(75) | 74006 |
B″ | 4901.545(10) | 5034.435(10) | |
C″ | 4379.740(10) | 4472.449(10) |