SCSe

Molecular parameters

Parameters Vib. State
υ1 υ2 υ3
32S12C82Se 32S12C80Se 32S12C78Se 32S12C76Se Ref.
Bυ [MHz] a 0 00 0 2027.113 2043.310 2060.321 2078.190 71022
Bυ [MHz]  0 11 0 2031.229(5) 2047.443(3) 2064.490(3) 2082.405(5)
0 22 0 2035.345(5) 2051.576(3) 2068.659(3) 2086.620(5)
qυ [MHz] 0 11 0 0.996(5) 1.005(3) 1.021(3) 1.041(5)
DJ [kHz]     0.163(40) 0.225(150)  
µ [C · m]
     µ [D]
0 22 0   0.103(17) x 10-30 
     0.031(5)
   

a The rotational constants for the ground vibrational state were extrapolated from those derived for the excited vibrational states. These are believed to be more accurate than the values derived from measurements reported in [50013].


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