Watson's Determinable Parameters |
80SeO2 a [MHz] |
78SeO2 a [MHz] |
---|---|---|
A″ | 28 826.381(92) | 29 037.626(105) |
B″ | 8676.6008(284) | 8676.4604(382) |
C″ | 6651.8491(266) | 6663.0034(323) |
τ1 | 0.111 01(2149) | 0.170 91(3596) |
τ2 | 0.008 619(4323) | 0.020 37(744) |
τ3 b | 0.10(6) | -0.05(10) |
τaaaa | -2.2166(133) | -2.2107(217) |
τbbbb | -0.047 283(2327) | -0.041 080(3764) |
τcccc | ||
Std. dev. | 0.244 | 0. 265 |
No. lines fit | 26 | 23 |
µb [D] |
2.62(5) c |
|
Derived Parameters (assuming planarity conditions) |
||
A′ | 28 826.373(92) | 29 037.620(105) |
B′ | 8676.603(27) | 8676.469(35) |
C′ | 6651.910(28) | 6663.086(32) |
τ′bbcc | -0.0166(17) | -0.0121(31) |
τ′ccaa | 0.018(11) | |
τ′aabb | 0.123(15) | 0.165(23) |
τaabb(1) | 0.2106(69) | 0.229(17) |
τaabb(2) | 0.2088(79) | 0.2365(90) |
τaabb(3) | 0.2088(79) | 0.2365(90) |
τabab(1) | -0.0440(44) | -0.0322(54) |
τabab(2) | -0.0424(71) | -0.038(13) |
τabab(3) | -0.0421(79) | -0.039(16) |
Δτ |
a The uncertainties quoted are one standared
deviation as estimated by the least squares fit. The number of significant
figures quoted are necessary to reproduce the calculated transition frequencies
within their standard deviations.
b Strictly speaking, τ3 is not a determinable parameter, but is calculated from τ1, τ2, τaaaa, and τbbbb using the planarity conditions. |
Isotopic Species |
Vib. State υ1 υ2 υ3 |
A [MHz] |
B [MHz] |
C [MHz] |
Ref. |
---|---|---|---|---|---|
82Se16O2 | 0 0 0 | 28 624.76 | 8676.47 | 6640.98 | 70035 |
80Se16O2 a | 1 0 0 | 28 763.70(72) | 8640.26(18) | 6623.25(27) | |
0 1 0 | 29 261.86(57) | 8677.27(18) | 6638.58(12) | ||
0 2 0 | 29 712.50(80) | 8677.63(40) | 6625.06(40) | ||
0 0 1 | 28 651.43(80) | 8649.49(30) | 6631.49(30) | ||
78Se16O2 a | 1 0 0 | 28 975.47 | 8640.09 | 6634.24 | |
0 1 0 | 29 477.03 | 8677.11 | 6649.60 | ||
0 0 1 | 28 858. 47 | 8649.33 | 6642.26 | ||
77Se16O2 | 0 0 0 | 29 146.70 | 8676.38 | 6668.68 | |
76Se16O2 | 0 0 0 | 29 260.12 | 8676.42 | 6674.17 |
a See table above for the ground state constants for these species.